2012
Ung, G.; Mendoza-Espinosa, D.; Bertrand G. Novel Route to Ynamides: Stable Ligands Equivalent to Unstable Oxazol-4-Ylidenes. Chem. Commun. 2012, 48, 7088-7090.
Abstract
Deprotonation of an oxazolium salt induces a ring opening process leading to the corresponding ynamide. Although the expected mesoionic carbene is not obtained, the acyclic ynamide readily reacts with various transition metals yielding robust mesoionic carbene complexes.
First Total Synthesis of ()-Flustraminol B
Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles
Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives
Synthesis of Bromoindole Alkaloids from Laurencia brongniartii
Role of lipid peroxidation in biliary obstruction in the rat
Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase
The absoluteconfiguration of cuauhtemone and related compounds
Stereochemical assignment of naturally occurring 2,3-epoxy-2-methylbutanoate esters