2012
Ung, G.; Mendoza-Espinosa, D.; Bertrand G. Novel Route to Ynamides: Stable Ligands Equivalent to Unstable Oxazol-4-Ylidenes. Chem. Commun. 2012, 48, 7088-7090.
Abstract
Deprotonation of an oxazolium salt induces a ring opening process leading to the corresponding ynamide. Although the expected mesoionic carbene is not obtained, the acyclic ynamide readily reacts with various transition metals yielding robust mesoionic carbene complexes.
Synthesis of Indolylindolines Mediated by tert-BuNH2
First Total Synthesis of ()-Flustraminol B
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters
Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles
Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling
Synthesis of 6-bromo-2-arylindoles using 2-iodobenzoic acid as precursor
Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase
Stereochemical assignment of naturally occurring 2,3-epoxy-2-methylbutanoate esters
Total Syntheses of Five Indole Alkaloids from the Marine Bryozoan Flustra foliacea