2011
Ung, G.; Mendoza-Espinosa, D.; Bouffard, J.; Bertrand, G. A Stable Acyclic Ligand Equivalent of an Unstable 1,3-Dithiol-5-ylidene. Angew. Chem. Int. Ed. 2011, 50, 4215-4218.
Abstract
Read the full textAbout AbstractSubstitutes you can rely on: Mesoionic carbenes (MICs) are not always stable. However, the acyclic ethynylcarbamodithioate 2 formed (instead of the corresponding MIC) by deprotonation of dithiolium salt 1 underwent cyclization to its precursor under acidic conditions and reacted with a variety of transition?metal centers to yield robust MIC complexes 3; (see scheme; Tipp=2,4,6?triisopropylphenyl).
One-potsynthesis of conformationallyrestrictedspirooxindoles
Role of lipid peroxidation in biliary obstruction in the rat
The absoluteconfiguration of cuauhtemone and related compounds
Aromatic Bromination versus Oxidation of Indolylmalonates by Bromine
Regioselective Synthesis of 3-Indolyl(alkoxy)acetates
Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling
Synthesis of Bromoindole Alkaloids from Laurencia brongniartii
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters