2010
Mendoza-Espinosa, D.; Donnadieu, B.; Bertrand, G. Synthesis of a Variety of 4,5-Functionalized Imidazol-2-Ylidenes from a Single 4,5-Unsubstituted Imidazol-2-Ylidene. J. Am. Chem. Soc. 2010, 132, 7264-7265.
Abstract
Using the nucleophilicity of NHCs and aNHCs, as well as the leaving group ability of the former, the carbon?carbon double bond of imidazol-2-ylidenes can be readily mono- and difunctionalized. These results provide also a new light on the formation of abnormal carbene adducts from classical unsaturated NHCs.
Synthesis of Indolylindolines Mediated by tert-BuNH2
Trapping enols of esters and lactones with diazomethane
First Total Synthesis of ()-Flustraminol B
Cleavage of alkoxycarbonyl protecting groups from carbamates by t-BuNH2
Aromatic Bromination versus Oxidation of Indolylmalonates by Bromine
Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles
One-potsynthesis of conformationallyrestrictedspirooxindoles
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters