Expedient synthesis of highly functionalized abnormal gold complexes.
Mendoza Espinosa, Daniel
2018
Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.
Abstract
The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups
Artículos relacionados
The absoluteconfiguration of cuauhtemone and related compounds
Total Syntheses of Five Indole Alkaloids from the Marine Bryozoan Flustra foliacea
Synthesis of Indolylindolines Mediated by tert-BuNH2
Trapping enols of esters and lactones with diazomethane
Synthesis of Bromoindole Alkaloids from Laurencia brongniartii
Stereochemical assignment of naturally occurring 2,3-epoxy-2-methylbutanoate esters
Role of lipid peroxidation in biliary obstruction in the rat
Aromatic Bromination versus Oxidation of Indolylmalonates by Bromine