2017
Visible-Light-Promoted AuI to AuIII Oxidation in Triazol-5-ylidene Complexes, Daniel Mendoza-Espinosa, David Rendon-Nava, Alejandro Alvarez-Hernandez, Deyanira Angeles-Beltran, Guillermo E. Negron-Silva, Oscar R. Suarez-Castillo, Chem. Asian J. 2017, 12, 203 - 207
Abstract
Reaction of triazolium precursors [MIC(CH2)n? H+]I? (n=1?3) with potassium hexamethyldisilazane (KHMDS) and AuCl(SMe2) generates the gold(I) complexes of the type MIC(CH2)n?AuI. Visible light exposure of the latter complexes promotes a spontaneous disproportionation process rendering gold(III) complexes of the type [{MIC(CH2)n}2?AuI2]+I?. Both the AuI and AuIII complex series were tested in the catalytic hydrohydrazination of terminal alkynes using hydrazine as nitrogen source.
Synthesis of Bromoindole Alkaloids from Laurencia brongniartii
Transesterifications mediated by t-BuNH2
Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles
One-potsynthesis of conformationallyrestrictedspirooxindoles
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters
Synthesis of 6-bromo-2-arylindoles using 2-iodobenzoic acid as precursor
Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives
The absoluteconfiguration of cuauhtemone and related compounds