Producción Científica Profesorado

O-Ethyl S-{(S)-1-oxo-1-[(R)-2-oxo-4-phenyloxazolidin-3-yl]propan-2-yl} Carbonodithioate.



Lopez Ruíz, Heraclio

2014

O-Ethyl S-{(S)-1-oxo-1-[(R)-2-oxo-4-phenyloxazolidin-3-yl]propan-2-yl} Carbonodithioate, J. Pablo García-Merinos, Heraclio López-Ruiz, Yliana López y Susana Rojas-Lima,Acta Crystallographica Section E, E70, o584-o585, (2014). DOI:10.1107/S1600536814007636


Abstract


In the title compound, C15H17NO4S2, synthesized by additionof O-ethylxanthic acid potassium salt to a diastereomericmixture of (4R)-3-(2-chloropropanoyl)-4-phenyloxazolidin-2-one, the oxazolidinone ring has a twist conformation on theC?C bond. The phenyl ring is inclined to the mean plane ofthe oxazolidinone ring by 76.4 (3). In the chain the methine Hatom is involved in a C?H S and a C?H O intramolecularinteraction. In the crystal, molecules are linked byC?H interactions, forming chains along [001]. The Sconfiguration at the C atom to which the xanthate group isattached was determined by comparison to the known Rconfiguration of the C atom to which the phenyl group isattached.



Producto de Investigación




Artículos relacionados

Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes.

Furocoumarins of three species of the genus Dorstenia

Facile synthesis of 1,3,6-oxadiazepines from 2,2?-(1,2-ethanediyldiimino)bisphenols

Study of the reactivity of squarylferrocenes. Addition of amines and aminoesters

Comparative Structural Characterization of the Biquaternized N-CH3 and N-BH3 Derivatives of the cis-...

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reaction

Phenylboronic acid catalyzed-cyanide promoted, one-pot synthesis of 2-(2-hydroxyphenyl)benzoxazole d...

Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles

Preparation of Seven- and Eight-Membered Boron Heterocycles from Different Salen Ligands and Arylbor...

Synthesis of nitrogen-, oxygen- and sulphur-containing tripodal ligands with a trimethylbenzene core...