Producción Científica Profesorado

O-Ethyl S-{(S)-1-oxo-1-[(R)-2-oxo-4-phenyloxazolidin-3-yl]propan-2-yl} Carbonodithioate.



Lopez Ruíz, Heraclio

2014

O-Ethyl S-{(S)-1-oxo-1-[(R)-2-oxo-4-phenyloxazolidin-3-yl]propan-2-yl} Carbonodithioate, J. Pablo García-Merinos, Heraclio López-Ruiz, Yliana López y Susana Rojas-Lima,Acta Crystallographica Section E, E70, o584-o585, (2014). DOI:10.1107/S1600536814007636


Abstract


In the title compound, C15H17NO4S2, synthesized by additionof O-ethylxanthic acid potassium salt to a diastereomericmixture of (4R)-3-(2-chloropropanoyl)-4-phenyloxazolidin-2-one, the oxazolidinone ring has a twist conformation on theC?C bond. The phenyl ring is inclined to the mean plane ofthe oxazolidinone ring by 76.4 (3). In the chain the methine Hatom is involved in a C?H S and a C?H O intramolecularinteraction. In the crystal, molecules are linked byC?H interactions, forming chains along [001]. The Sconfiguration at the C atom to which the xanthate group isattached was determined by comparison to the known Rconfiguration of the C atom to which the phenyl group isattached.



Producto de Investigación




Artículos relacionados

Synthesis of new homochiral 2,3-dialkylpiperazines derived from (R)-(?)-phenylglycinol

A flexible access to highly functionalised boronates

Synthesis and Structures of some Lithium and Sodium (Aminoalcoholato)hydrido Aluminates

r-Alkylation of (S)-Asparagine with Self-Regeneration of the Stereogenic Center: Enantioselective Sy...

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

The Structural Chemistry of N-Monolithium Borazines

Structural studies of spiroarsoranes derived from 2-aminophenols

Synthesis of New Chiral Derivatives of N,N?-Dimethylpropyleneurea (DMPU) and Examination of Their In...

Effect of TiO2Al2O3 SolGel Supports on the Superficial Ni and Mo Species in Oxidized and Sulfided Ni...

Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles