2014
O-Ethyl S-{(S)-1-oxo-1-[(R)-2-oxo-4-phenyloxazolidin-3-yl]propan-2-yl} Carbonodithioate, J. Pablo García-Merinos, Heraclio López-Ruiz, Yliana López y Susana Rojas-Lima,Acta Crystallographica Section E, E70, o584-o585, (2014). DOI:10.1107/S1600536814007636
Abstract
In the title compound, C15H17NO4S2, synthesized by additionof O-ethylxanthic acid potassium salt to a diastereomericmixture of (4R)-3-(2-chloropropanoyl)-4-phenyloxazolidin-2-one, the oxazolidinone ring has a twist conformation on theC?C bond. The phenyl ring is inclined to the mean plane ofthe oxazolidinone ring by 76.4 (3). In the chain the methine Hatom is involved in a C?H S and a C?H O intramolecularinteraction. In the crystal, molecules are linked byC?H interactions, forming chains along [001]. The Sconfiguration at the C atom to which the xanthate group isattached was determined by comparison to the known Rconfiguration of the C atom to which the phenyl group isattached.
Study of the reactivity of squarylferrocenes. Addition of amines and aminoesters
Furocoumarins of three species of the genus Dorstenia
Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes.
Aroylthioureas: new organic ionophores for heavy-metal ion selective electrodes
A flexible access to highly functionalised boronates
Preparation of N-aryl-substituted spiro-?-lactams via Staudinger cycloaddition
Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reaction