Producción Científica Profesorado

Study of the reactivity of squarylferrocenes. Addition of amines and aminoesters



Alvarez Hernandez, Alejandro

2011

Villanueva-García Fabián, Reyes Priscilla, Keith H. Pannell, Álvarez-Hernández Alejandro , Valois Ismael, Juárez-Ruiz Juan M., Flores-Rizo Juan O., and Peña-Cabrera Eduardo. Study of the reactivity of squarylferrocenes. Addition of amines and aminoesters. ARKIVOC 2011, (ix) 105-124. Arkat USA. Estados Unidos.


Abstract


The reactivity of squarylferrocenes was studied in the addition of several N-centered nucleophiles. A total of seven simple amines (primary and secondary) were added to both monosquarylferrocene and 1,1?-bissquarylferrocene to generate 14 ferrocenylsquaramides in 85-98%. Likewise, five aminoesters were added to the same scaffolds to produce a novel family of 10 ferrocene-aminoester conjugates in good to excellent yields (57-95%).



Producto de Investigación




Artículos relacionados

Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)

Synthesis and Structures of some Lithium and Sodium (Aminoalcoholato)hydrido Aluminates

Preparation of N-aryl-substituted spiro-?-lactams via Staudinger cycloaddition

Highly diastereoselective alkylation, acylation and aldol condensation of cis- and trans-(N-acyloyl)...

Cathepsins X and B Can Be Differentiated through Their Respective Mono- and Dipeptidyl Carboxypeptid...

Furocoumarins of three species of the genus Dorstenia

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reactio

Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes