Producción Científica Profesorado

Study of the reactivity of squarylferrocenes. Addition of amines and aminoesters



Alvarez Hernandez, Alejandro

2011

Villanueva-García Fabián, Reyes Priscilla, Keith H. Pannell, Álvarez-Hernández Alejandro , Valois Ismael, Juárez-Ruiz Juan M., Flores-Rizo Juan O., and Peña-Cabrera Eduardo. Study of the reactivity of squarylferrocenes. Addition of amines and aminoesters. ARKIVOC 2011, (ix) 105-124. Arkat USA. Estados Unidos.


Abstract


The reactivity of squarylferrocenes was studied in the addition of several N-centered nucleophiles. A total of seven simple amines (primary and secondary) were added to both monosquarylferrocene and 1,1?-bissquarylferrocene to generate 14 ferrocenylsquaramides in 85-98%. Likewise, five aminoesters were added to the same scaffolds to produce a novel family of 10 ferrocene-aminoester conjugates in good to excellent yields (57-95%).



Producto de Investigación




Artículos relacionados

Synthesis, crystal structures, and quadratic nonlinear optical properties in a series of pushpull bo...

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...

Synthesis and Study of Isomeric Benzo[1,4]oxazines and Benzothiazolines by NMR Spectroscopy and X-Ra...

New boronates prepared from 2,4-pentanedione derived ligands of the NO2 and N2O2 type comparison to...

Synthesis of nitrogen-, oxygen- and sulphur-containing tripodal ligands with a trimethylbenzene core...

Structural studies of spiroarsoranes derived from 2-aminophenols

Addition reaction of benzylbenzylidenenamine to lithium enolates of 1,3-dioxolan-4-one: synthesis of...

A practical access to acyl radicals from acyl hydrazides

Phenylmethyl 2,3,4-tri-O-acetyl--D-fucopyranoside

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reaction