Producción Científica Profesorado

Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes.



Lopez Ruíz, Heraclio

2007

Juan Pablo, García-Merinos, Juan Pablo Hernández-Pérez, Leonel Martínez-García, Susana Rojas-Lima, Heraclio López Ruiz. Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes. Journal of the Mexican Chemical Society, 51(4), 209-212.(2007)


Abstract


The triethylborane mediated intermolecular addition ofdiverse carbon radicals, derived from the corresponding xanthates,to allyl acetate (10b) and 4-allyl-1,2-dimethoxybenzene (10a) wasstudied in various solvents. In most cases, the product yields in waterat room temperature were as good as, or better than, those obtainedusing 1,2-dichloroethane as the solvent. In contrast, ethanol in mostcases was not a useful solvent in which to conduct these reactions.



Producto de Investigación




Artículos relacionados

Synthesis of New Chiral Derivatives of N,N?-Dimethylpropyleneurea (DMPU) and Examination of Their In...

Synthesis and Study of Isomeric Benzo[1,4]oxazines and Benzothiazolines by NMR Spectroscopy and X-Ra...

Phenylboronic acid catalyzed-cyanide promoted, one-pot synthesis of 2-(2-hydroxyphenyl)benzoxazole d...

Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes

Effect of TiO2Al2O3 SolGel Supports on the Superficial Ni and Mo Species in Oxidized and Sulfided Ni...

Synthesis, crystal structures, and quadratic nonlinear optical properties in a series of pushpull bo...

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reactio

Facile synthesis of 1,3,6-oxadiazepines from 2,2?-(1,2-ethanediyldiimino)bisphenols

The Structural Chemistry of N-Monolithium Borazines

Addition reaction of benzylbenzylidenenamine to lithium enolates of1,3-dioxolan-4-one: synthesis of ...