Producción Científica Profesorado

Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes.



Lopez Ruíz, Heraclio

2007

Juan Pablo, García-Merinos, Juan Pablo Hernández-Pérez, Leonel Martínez-García, Susana Rojas-Lima, Heraclio López Ruiz. Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes. Journal of the Mexican Chemical Society, 51(4), 209-212.(2007)


Abstract


The triethylborane mediated intermolecular addition ofdiverse carbon radicals, derived from the corresponding xanthates,to allyl acetate (10b) and 4-allyl-1,2-dimethoxybenzene (10a) wasstudied in various solvents. In most cases, the product yields in waterat room temperature were as good as, or better than, those obtainedusing 1,2-dichloroethane as the solvent. In contrast, ethanol in mostcases was not a useful solvent in which to conduct these reactions.



Producto de Investigación




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