Producción Científica Profesorado


Rojas Lima, Susana


Luis Alberto Montiel Ortega, Susana Rojas-Lima, Elena Otazo Sanchez, Roberto Villagómez Ibarra. O-benzyl-N-(2-furoyl)thiocarbamate. Journal of Chemical Crystallography 34, 2, 89-93 (2004).


The O-benzyl-N-(2-furoyl)thiocarbamate (1) was obtained by direct reaction between furoyl isothiocyanate and benzyl alcohol. The X-ray diffraction analysis of 1 showed an orthorhombic system, with a = 7.811(4) Å, b = 9.685(4) Å, c = 33.562(15) Å, and space group P212121. This compound showed two different arrays of structure, corresponding to two conformers in the same crystal unit. In one conformer the carbonyl and thiocarbonyl groups are in a syn arrangement while in the other the groups are anti. Both structures present a non-restricted conformation and show NH\bondOC hydrogen bonding between them.

Producto de Investigación

Artículos relacionados

Highly diastereoselective alkylation, acylation and aldol condensation of cis- and trans-(N-acyloyl)...

Enantioselective synthesis of ?-amino acids. Part 10: Preparation of novel ?,?- and ?,?-disubstitute...

A practical access to acyl radicals from acyl hydrazides

X-ray crystallographic study of neutral boron chelates with ?-diketones and tropolone

3-Benzoyl-2-isopropyl-4-alkyloxazolidin-5-ones as Efficient and Inexpensive Sources of Enantiopure ?...

Diastereomeric C-glycosyloxanthrones from picramnia antidesma

Aroylthioureas: new organic ionophores for heavy-metal ion selective electrodes

Preparation of N-aryl-substituted spiro-?-lactams via Staudinger cycloaddition

r-Alkylation of (S)-Asparagine with Self-Regeneration of the Stereogenic Center: Enantioselective Sy...

Ylidaddukte der Penteltrichloride