Producción Científica Profesorado

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipyridyl ligands



Páez Hernández, María Elena

2008

Andrade-López, N., Alvarado-Rodríguez, J.G., González-Montiel, S., Páez-Hernández, M.E.,Galán-Vidal, C.A., Jiménez-Pérez, A. Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipyridyl ligands. ARKIVOC, 2008 (v) 43-54. ISSN 1424-6376


Abstract


Coordinative behavior of the di-(2-pyridyl)hydroxymethane (1) and di-(2-pyridyl)-2-pyridylsulfanylmethane (2) ligands towards Pd(II) and Pt(II) is described. The compounds 3-5 were characterized by IR, mass spectrometry and NMR spectroscopy. Crystal structures of [Pt{(C5H4N)2CH(OH)}Cl2] 3 and [Pd{(C5H4N)2CH(2-C5H4NS)}Cl2] 4 as DMSO solvates displayed the formation of neutral mononuclear complexes. In the complexes 3 and 4 is observed the formation of six-membered chelate rings. The local geometry of the metallic atoms can be described as square planar in the title complexes.



Producto de Investigación




Artículos relacionados

Potentiometric quantification of saccharin by using a selective membrane formed by pyrrole electropo...

Prevalence and Antimicrobial Resistance Patterns of Salmonella from Different Raw Foods in Mexico

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipy...

Renewable stationary phase liquid magnetochromatography: determining aspartame and its hydrolysis pr...

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

Multicommutated Anodic Stripping Voltammetry at Tubular Bismuth Film Electrode for Lead Determinatio...

Metal content evaluation and its effect on the stability of anthocyanins

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2

Determination of tetracyclines in milk samples by magnetic solid phase extraction flow injection ana...

Chemical studies of anthocyanins: A review