Expedient synthesis of highly functionalized abnormal gold complexes.
Mendoza Espinosa, Daniel
2018
Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.
Abstract
The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups
Artículos relacionados
Trapping enols of esters and lactones with diazomethane
Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling
Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters
Synthesis of Acetamido(indol-3-yl)propanol Derivatives
Role of lipid peroxidation in biliary obstruction in the rat
Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles
The absoluteconfiguration of cuauhtemone and related compounds
Stereochemical assignment of naturally occurring 2,3-epoxy-2-methylbutanoate esters
Synthesis of Bromoindole Alkaloids from Laurencia brongniartii