Expedient synthesis of highly functionalized abnormal gold complexes.
Mendoza Espinosa, Daniel
2018
Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.
Abstract
The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups
Artículos relacionados
Total Syntheses of Five Indole Alkaloids from the Marine Bryozoan Flustra foliacea
Synthesis of Bromoindole Alkaloids from Laurencia brongniartii
First Total Synthesis of ()-Flustraminol B
Regioselective Synthesis of 3-Indolyl(alkoxy)acetates
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters
Synthesis of Indolylindolines Mediated by tert-BuNH2
The absoluteconfiguration of cuauhtemone and related compounds
Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles
Synthesis of 6-bromo-2-arylindoles using 2-iodobenzoic acid as precursor