Expedient synthesis of highly functionalized abnormal gold complexes.
Mendoza Espinosa, Daniel
2018
Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.
Abstract
The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups
Artículos relacionados
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters
Aromatic Bromination versus Oxidation of Indolylmalonates by Bromine
Total Syntheses of Five Indole Alkaloids from the Marine Bryozoan Flustra foliacea
Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles
Synthesis of Acetamido(indol-3-yl)propanol Derivatives
The absoluteconfiguration of cuauhtemone and related compounds
Cleavage of alkoxycarbonyl protecting groups from carbamates by t-BuNH2
Trapping enols of esters and lactones with diazomethane
Role of lipid peroxidation in biliary obstruction in the rat
Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives