Producción Científica Profesorado

Expedient synthesis of highly functionalized abnormal gold complexes.



Mendoza Espinosa, Daniel

2018

Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.


Abstract


The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups






Artículos relacionados

Aromatic Bromination versus Oxidation of Indolylmalonates by Bromine

Reactivity of TpMe2Ir(C2H4)(DMAD) with carboxylic acids. A DFT study on geometrical isomers and stru...

Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles

Cascade [1,3]-Sigmatropic Rearrangements of Ketene O,O-Acetals: Kinetic and DFT Level Mechanistic St...

Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling

Synthesis of ?4:?2-Exocyclic-Diene Iridium(I) Complexes Derived from 1,3-Oxazolidin-2-ones and Their...

13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters

Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives

Synthesis of 6-bromo-2-arylindoles using 2-iodobenzoic acid as precursor

Synthesis of Acetamido(indol-3-yl)propanol Derivatives