Producción Científica Profesorado

Expedient synthesis of highly functionalized abnormal gold complexes.



Mendoza Espinosa, Daniel

2018

Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.


Abstract


The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups






Artículos relacionados

Cleavage of alkoxycarbonyl protecting groups from carbamates by t-BuNH2

Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles

The absoluteconfiguration of cuauhtemone and related compounds

Preparation of 3-hydroxyoxindoles with dimethyldioxirane and their use for the synthesis of natural ...

Conformationalstudies of N-carbomethoxy-2-alkoxyindolenines by dynamic NMR, crystallography, and mol...

First Total Synthesis of ()-Flustraminol B

Transesterifications mediated by t-BuNH2

Trapping enols of esters and lactones with diazomethane

Reactivity of TpMe2Ir(C2H4)(DMAD) with carboxylic acids. A DFT study on geometrical isomers and stru...

One-potsynthesis of conformationallyrestrictedspirooxindoles