Synthesis and characterization of monoanionic salts of p-tertbutylcalix[7]arene
Mendoza Espinosa, Daniel
2018
Synthesis and characterization of monoanionic salts of p-tertbutylcalix[7]arene, Mariana Flores-Jarillo, Simplicio Gonzalez-Montiel, Verónica Salazar-Pereda, Daniel Mendoza-Espinosa, Journal of Organometallic Chemistry 862 (2018) 53-57
Abstract
The synthesis and full characterization of a new series of p-tert-butylcalix [7]arene (tBuC7) monoanionsof the type tBuC7M (M Na, K, Rb, Cs) is reported. Crystal structures of tBuC7K and tBuC7Rb featuremonomeric units and represent the first examples of solid state characterized tBuC7 salts. The alkalimetal base strength and reaction stoichiometry used for the selective formation of monoanionic speciesis discussed.
Artículos relacionados
Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives
Transesterifications mediated by t-BuNH2
Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase
The absoluteconfiguration of cuauhtemone and related compounds
Trapping enols of esters and lactones with diazomethane
First Total Synthesis of ()-Flustraminol B
Synthesis of 6-bromo-2-arylindoles using 2-iodobenzoic acid as precursor
Total Syntheses of Five Indole Alkaloids from the Marine Bryozoan Flustra foliacea