Producción Científica Profesorado

Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexes with a C4 Symmetric Tetratriazol-5-ylidene



González Montiel, Simplicio

2017

Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexeswith a C4?Symmetric Tetratriazol-5-ylideneMariana Flores-Jarillo, Daniel Mendoza-Espinosa,* Verónica Salazar-Pereda, Simplicio González-Montiel, Organometallics, 2017doi:10.1021/acs.organomet.7b00712


Abstract


The facile preparation of a C4-symmteric tetratriazolium salt and its subsequent metalation to generate a series of tetranuclear mesoionic carbene gold(I) complexes is presented. The complete structural characterization of the metallic carbenes and the benefits of cooperative catalysis in the processes of hydroamination and hydrohydrazination of terminal alkynes are discussed.



Producto de Investigación



Artículos relacionados

Study of the D?Sb (D = O, S) Transannular Interaction in Sb-Monohalogenated Dibenzostibocines ? An E...

Synthesis and crystal structure of the N-8-(diphenyl-hydroxy-2-aminomethylpyridine)borane

Pentacoordination at Germanium by Transannular Bonding of Sulfur or Oxygen in an Eight-Membered Ring...

Six-membered ring chelate complexes of Pd(II) and Pt(II) derived from di-(2-pyridyl)pyrimidin-2-ylsu...

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2

Structural differences in eight- and ten-membered heterocyclic tin compounds displaying transannular...

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipy...

Versatile behavior of 2-guanidinobenzimidazole nitrogen atoms toward protonation, coordination and m...

Determination of Glucose by Flow Injection Analysis with Amperometric Detection at Fe(III)-(tris(3,5...

Synthesis, characterization and crystal structures of dipyridyl-N-methylimine and cloro-bis (N,N?-2,...