Producción Científica Profesorado

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2



Andrade López, Noemí

2010

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2. Francisco Pérez-García, José G. Alvarado-Rodríguez, Carlos Andrés. Galán-Vidal, María Elena. Páez-Hernández, , Noemí Andrade-López, Rafael Moreno-Esparza, Struct. Chem., 21 (2010) 191-196. ISSN: 1040-0400 (print version) ISSN: 1572-9001 (electronic version) DOI: 10.1007/s11224-009-9562-5


Abstract


Treatment of KS2P(OC6H4)2 (1) with five n-alkyl halides afforded the stable n-alkyldithiophosphate compounds RS2P(OC6H4)2 (26). Single crystal X-ray analysis revealed that the PS2 fragment in 1 displays an isobidentate coordination pattern; compounds 24 display a monodentate binding pattern. The crystal packing of title compounds is stabilized by cation-?, weak hydrogen bonding CH---O, as well as aromatic non-bonded interactions.



Producto de Investigación




Artículos relacionados

Boron heterocycles derived from 2-guanidinobenzimidazole

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2

Understanding and Predicting Distorted T- versus Y-Geometries for Neutral Chromous Complexes Support...

Pentacoordination at Germanium by Transannular Bonding of Sulfur or Oxygen in an Eight-Membered Ring...

Hypervalence at tin(IV) by transannular bonding of sulfur in an eight-membered ring: The case of dib...

Six-membered ring chelate complexes of Pd(II) and Pt(II) derived from di-(2-pyridyl)pyrimidin-2-ylsu...

Organometallic tin complexes derived from 2-guanidinobenzimidazole

Determination of Glucose by Flow Injection Analysis with Amperometric Detection at Fe(III)-(tris(3,5...

Study of the D?Sb (D = O, S) Transannular Interaction in Sb-Monohalogenated Dibenzostibocines ? An E...

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...