Producción Científica Profesorado

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipyridyl ligands



González Montiel, Simplicio

2008

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipyridyl ligands.Noemí Andrade-López, José G. Alvarado-Rodríguez, Simplicio González-Montiel, Carlos-Andrés Galán-Vidal, María Elena Páez-Hernández, Araceli Jiménez-Pérez, ARKIVOC (2008) 43-54. ISSN 1424-6376.


Abstract


Coordinative behavior of the di-(2-pyridyl)hydroxymethane (1) and di-(2-pyridyl)-2-pyridylsulfanylmethane (2) ligands towards Pd(II) and Pt(II) is described. The compounds 3-5 were characterized by IR, mass spectrometry and NMR spectroscopy. Crystal structures of [Pt{(C5H4N)2CH(OH)}Cl2] 3 and [Pd{(C5H4N)2CH(2-C5H4NS)}Cl2] 4 as DMSO solvates displayed the formation of neutral mononuclear complexes. In the complexes 3 and 4 is observed the formation of six-membered chelate rings. The local geometry of the metallic atoms can be described as square planar in the title complexes.



Producto de Investigación




Artículos relacionados

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2

Benzazole-N(SINGLE BOND)BH3 adducts. Reductive transposition of 2-benzimidazole, 2-benzothiazole, an...

Pentacoordination at Germanium by Transannular Bonding of Sulfur or Oxygen in an Eight-Membered Ring...

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

Synthesis, Characterisation and Properties of As-Monohalogenated Dibenzoarsocines S(C6H4S)2AsHal (Ha...

Synthesis, characterization and crystal structures of organolead dithiolate compounds displaying tra...

Boron heterocycles derived from 2-guanidinobenzimidazole

Hypervalence at tin(IV) by transannular bonding of sulfur in an eight-membered ring: The case of dib...

Structural differences in eight- and ten-membered heterocyclic tin compounds displaying transannular...