Producción Científica Profesorado

Hexacoordinated spirocyclic germanium(IV) complex: Synthesis and structural characterization



González Montiel, Simplicio

2009

Hexacoordinated Spirocyclic Germanium(IV) Complex: Synthesis and StructuralCharacterization, Simplicio González Montiel, Raymundo Cea Olivares, Vojtech Jancik, Leslie W. Pineda, Rubén A. Toscano, Heteroatom Chemistry, 2009, 20, 4549.,DOI: 10.1002/hc.2051, ISSN: 1098-107,


Abstract


The spiro-dibenzogermocine [O(o-C6H4S)2]2Ge (1) was prepared in a reaction between O(o-C6H4SH)2 and Ge(OiPr)4, and its molecular structure was determined by X-ray diffraction studies. In the solid state, 1 shows the existence of two weak O ? Ge transannular interactions, resulting in a hexacoordinated germanium atom that displays the geometry of a distorted bicapped tetrahedron.



Producto de Investigación




Artículos relacionados

Study of the D?Sb (D = O, S) Transannular Interaction in Sb-Monohalogenated Dibenzostibocines ? An E...

Synthesis, characterization and crystal structures of dipyridyl-N-methylimine and cloro-bis (N,N?-2,...

Versatile behavior of 2-guanidinobenzimidazole nitrogen atoms toward protonation, coordination and m...

Structural differences in eight- and ten-membered heterocyclic tin compounds displaying transannular...

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2

Synthesis and crystal structure of the N-8-(diphenyl-hydroxy-2-aminomethylpyridine)borane

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

Determination of Glucose by Flow Injection Analysis with Amperometric Detection at Fe(III)-(tris(3,5...

Synthesis, characterization and crystal structures of organolead dithiolate compounds displaying tra...

Synthesis and structural characterization of bis-chelate Pd(II) complexes derived from substituted d...