Hexacoordinated spirocyclic germanium(IV) complex: Synthesis and structural characterization
González Montiel, Simplicio
2009
Hexacoordinated Spirocyclic Germanium(IV) Complex: Synthesis and StructuralCharacterization, Simplicio González Montiel, Raymundo Cea Olivares, Vojtech Jancik, Leslie W. Pineda, Rubén A. Toscano, Heteroatom Chemistry, 2009, 20, 4549.,DOI: 10.1002/hc.2051, ISSN: 1098-107,
Abstract
The spiro-dibenzogermocine [O(o-C6H4S)2]2Ge (1) was prepared in a reaction between O(o-C6H4SH)2 and Ge(OiPr)4, and its molecular structure was determined by X-ray diffraction studies. In the solid state, 1 shows the existence of two weak O ? Ge transannular interactions, resulting in a hexacoordinated germanium atom that displays the geometry of a distorted bicapped tetrahedron.
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