Producción Científica Profesorado

Evaluation of hydrogen bonds in hydrobenzothiazoles 2-pyridin substituted.



Andrade López, Noemí

2016

Evaluation of hydrogen bonds in hydrobenzothiazoles 2-pyridin substituted. Jesús Alberto Alvarez-Hernández, Uvaldo Hernández-Balderas, Simplicio González-Montiel, José Guadalupe Alvarado-Rodríguez, Noemí Andrade-López*. Pädi (2016), 6. ISSN 2007-6363


Abstract


In this work, the study of hydrogen bonds in the hydrobenzothiazoles 2-pyridin substituted of general formula {(C6H4CSNH)(C5H4N)R} [(1), R = H; (2), R = C6H5; (3), R = C5H4N] in solution and solid state by NMR, infrared and X-ray diffraction is described, Figure 1. On the one hand, for 2 and 3, the 1H NMR data in CDCl3 solution displayed the predominance of an intramolecular hydrogen bonding NH???N that is formed between the hydrogen atom of the NH group with the pyridinic nitrogen atom forming a five-membered ring. On the other hand, the 1H NMR spectra of 1 ? 3 in DMSO-d6 solution showed the formation of intermolecular hydrogen bonds of type NH???OS(CH3)2. In solid state, the NH???N intramolecular hydrogen bonding for 1 ? 3 by infrared and X-ray diffraction has been also established.



Producto de Investigación




Artículos relacionados

Synthesis and Crystal Structure of [Te{S(C6H3S)2O}]: A Tetracyclic Tellurium(II) Compound Displaying...

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

Structural differences in eight- and ten-membered heterocyclic tin compounds displaying transannular...

Versatile behavior of 2-guanidinobenzimidazole nitrogen atoms toward protonation, coordination and m...

Synthesis, Characterisation and Properties of As-Monohalogenated Dibenzoarsocines S(C6H4S)2AsHal (Ha...

Boron heterocycles derived from 2-guanidinobenzimidazole

Determination of Glucose by Flow Injection Analysis with Amperometric Detection at Fe(III)-(tris(3,5...

Hypervalence at tin(IV) by transannular bonding of sulfur in an eight-membered ring: The case of dib...

Five-membered ring chelate complexes of Ni(II), Pd(II) and Pt(II) derived of di-(2-pyridyl)-N-ethyli...

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipy...