The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}]
Rodríguez Ávila, José Antonio
2014
The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}], Gloria Sánchez-Cabrera, Francisco J. Zuno-Cruz, Heraclio López-Ruiz, María J. Rosales-Hoz, Marco A. Leyva y José A. Rodríguez, Journal of Organometallic Chemistry, 751, 826-829, (2014). DOI/10.1016/j.jorganchem.2013.08.035
Abstract
The cluster [{Os3(?-H)(CO)10}3{1,3,5-(?-SCH2)3C6H3}] has been prepared by the reaction of [Os3(CO)10(NCMe)2] with 1,3,5-tris(mercaptomethyl)benzene under mild conditions; the cluster has been fully characterized by IR, NMR spectroscopy, HR-MS, X-ray crystallography and its redox behavior is also described.
Artículos relacionados
Facilitated transport of Hg(II) through novel activated composite membranes
Mercury Ions Removal from Aqueous Solution Using an Activated Composite Membrane
Simultaneous determination of tetracyclines in poultry muscle by capillary zone electrophoresis
Characterization of Main Anthocyanins Extracted from Pericarp Blue Corn by MALDI-ToF MS