The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}]
Rodríguez Ávila, José Antonio
2014
The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}], Gloria Sánchez-Cabrera, Francisco J. Zuno-Cruz, Heraclio López-Ruiz, María J. Rosales-Hoz, Marco A. Leyva y José A. Rodríguez, Journal of Organometallic Chemistry, 751, 826-829, (2014). DOI/10.1016/j.jorganchem.2013.08.035
Abstract
The cluster [{Os3(?-H)(CO)10}3{1,3,5-(?-SCH2)3C6H3}] has been prepared by the reaction of [Os3(CO)10(NCMe)2] with 1,3,5-tris(mercaptomethyl)benzene under mild conditions; the cluster has been fully characterized by IR, NMR spectroscopy, HR-MS, X-ray crystallography and its redox behavior is also described.
Artículos relacionados
Facilitated transport of Hg(II) through novel activated composite membranes
Mercury Ions Removal from Aqueous Solution Using an Activated Composite Membrane
Metal content evaluation and its effect on the stability of anthocyanins
Determination of primary amino acids in wines by high performance liquid magneto-chromatography
Development of a novel composite sensor based on doped pyrrole selective to nitrate ions