Producción Científica Profesorado

O-Ethyl S-{(S)-1-oxo-1-[(R)-2-oxo-4-phenyloxazolidin-3-yl]propan-2-yl} Carbonodithioate



Rojas Lima, Susana

2014

O-Ethyl S-{(S)-1-oxo-1-[(R)-2-oxo-4-phenyloxazolidin-3-yl]propan-2-yl} Carbonodithioate, J. Pablo García-Merinos, Heraclio López-Ruiz, Yliana López y Susana Rojas-Lima,Acta Crystallographica Section E, E70, o584-o585, (2014). DOI:10.1107/S1600536814007636


Abstract


In the title compound, C15H17NO4S2, synthesized by additionof O-ethylxanthic acid potassium salt to a diastereomericmixture of (4R)-3-(2-chloropropanoyl)-4-phenyloxazolidin-2-one, the oxazolidinone ring has a twist conformation on theC?C bond. The phenyl ring is inclined to the mean plane ofthe oxazolidinone ring by 76.4 (3). In the chain the methine Hatom is involved in a C?H S and a C?H O intramolecularinteraction. In the crystal, molecules are linked byC?H interactions, forming chains along [001]. The Sconfiguration at the C atom to which the xanthate group isattached was determined by comparison to the known Rconfiguration of the C atom to which the phenyl group isattached.



Producto de Investigación




Artículos relacionados

Furocoumarins of three species of the genus Dorstenia

Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes.

Diastereomeric C-glycosyloxanthrones from picramnia antidesma

Structure-Activity Relationships for Inhibition of Cysteine Protease Activity and Development of Pla...

Ylidaddukte der Penteltrichloride

Addition reaction of benzylbenzylidenenamine to lithium enolates of1,3-dioxolan-4-one: synthesis of ...

Enantioselective synthesis of ?-amino acids. Part 10: Preparation of novel ?,?- and ?,?-disubstitute...

Aroylthioureas: new organic ionophores for heavy-metal ion selective electrodes

Study of the reactivity of squarylferrocenes. Addition of amines and aminoesters

Highly diastereoselective alkylation, acylation and aldol condensation of cis- and trans-(N-acyloyl)...