Producción Científica Profesorado

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)



Alvarez Hernandez, Alejandro

2004

Horacio Vásquez-Arciga, Aarón Pérez-Benítez, Alejandro Álvarez Hernández, Sylvain Bernesd and Miguel Ángel Méndez-Rojas. Bis(acetylsalicylato-k2O,O)diaquacadmium(II). Acta Crystallographica Section E Structure Reports. 2004, E60, m1621-m1623. ISSN 1600-5368. Reino Unido.


Abstract


In the title compound {systematic name: bis[2-(acetyloxy) benzoato-_2O,O0]diaquacadmium(II)}, [Cd(C9H7O4)2- (H2O)2], the CdII ion is located on a twofold rotation axis and is coordinated by two water molecules and two aspirinate ligands. The complex is almost isostructural with the corresponding zinc(II) complex. However, for the title compound, the aspirinate should be considered as an asymmetric chelating ligand, with CdÐO(carboxylate) bond lengths of 2.2777 (12) and 2.4121 (12) A Ê .



Producto de Investigación




Artículos relacionados

r-Alkylation of (S)-Asparagine with Self-Regeneration of the Stereogenic Center: Enantioselective Sy...

The Structural Chemistry of N-Monolithium Borazines

Addition reaction of benzylbenzylidenenamine to lithium enolates of 1,3-dioxolan-4-one: synthesis of...

Effect of TiO2Al2O3 SolGel Supports on the Superficial Ni and Mo Species in Oxidized and Sulfided Ni...

Structure-Activity Relationships for Inhibition of Cysteine Protease Activity and Development of Pla...

Diastereomeric C-glycosyloxanthrones from picramnia antidesma

Addition reaction of benzylbenzylidenenamine to lithium enolates of1,3-dioxolan-4-one: synthesis of ...

Structural studies of spiroarsoranes derived from 2-aminophenols

Cathepsins X and B Can Be Differentiated through Their Respective Mono- and Dipeptidyl Carboxypeptid...

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...