Producción Científica Profesorado

Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes



Rojas Lima, Susana

2007

Juan Pablo, García-Merinos, Juan Pablo Hernández-Pérez, Leonel Martínez-García, Susana Rojas-Lima, Heraclio López Ruiz. Et3, and efficient Mediattoo for Xanthate Transfer Based Radical Processes. Journal of the Mexican Chemical Society, 51(4), 209-212.(2007). ISSN 1870-249X


Abstract


The triethylborane mediated intermolecular addition of diverse carbon radicals, derived from the corresponding xanthates, to allyl acetate (10b) and 4-allyl-1,2-dimethoxybenzene (10a) was studied in various solvents. In most cases, the product yields in water at room temperature were as good as, or better than, those obtained using 1,2-dichloroethane as the solvent. In contrast, ethanol in most cases was not a useful solvent in which to conduct these reactions.



Producto de Investigación




Artículos relacionados

Synthesis and Study of Monomeric and Dimeric Boronates by Spectroscopic Methods and X-ray Crystallog...

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

The Structural Chemistry of N-Monolithium Borazines

Comparative Structural Characterization of the Biquaternized N-CH3 and N-BH3 Derivatives of the cis-...

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...

New boronates prepared from 2,4-pentanedione derived ligands of the NO2 and N2O2 type comparison to...

Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles

Furocoumarins of three species of the genus Dorstenia

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)

Synthesis of nitrogen-, oxygen- and sulphur-containing tripodal ligands with a trimethylbenzene core...