The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}],
Lopez Ruíz, Heraclio
2014
The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}],Gloria Sánchez-Cabrera, Francisco J. Zuno-Cruz, Heraclio López-Ruiz, María J. Rosales-Hoz, Marco A. Leyva y José A. Rodríguez, Journal of Organometallic Chemistry, 751, 826-829, (2014). DOI/10.1016/j.jorganchem.2013.08.035
Abstract
The reaction of the activated cluster [Os3(CO)10(NCMe)2] with 1,3,5-tris(mercaptomethyl)benzene as ligand, gave compound [{Os3(?-H)(CO)10}3{1,3,5-(?-SCH2)3C6H3}], as the sole identifiable product. The cluster has been fully characterized by IR, 1H and 13C NMR spectroscopy, HR-MS, X-ray crystallography and cyclic voltammetry.
Artículos relacionados
Study of the reactivity of squarylferrocenes. Addition of amines and aminoesters
Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes
Ylidaddukte der Penteltrichloride
Diastereomeric C-glycosyloxanthrones from picramnia antidesma
Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles