Producción Científica Profesorado

The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}],



Lopez Ruíz, Heraclio

2014

The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}],Gloria Sánchez-Cabrera, Francisco J. Zuno-Cruz, Heraclio López-Ruiz, María J. Rosales-Hoz, Marco A. Leyva y José A. Rodríguez, Journal of Organometallic Chemistry, 751, 826-829, (2014). DOI/10.1016/j.jorganchem.2013.08.035


Abstract


The reaction of the activated cluster [Os3(CO)10(NCMe)2] with 1,3,5-tris(mercaptomethyl)benzene as ligand, gave compound [{Os3(?-H)(CO)10}3{1,3,5-(?-SCH2)3C6H3}], as the sole identifiable product. The cluster has been fully characterized by IR, 1H and 13C NMR spectroscopy, HR-MS, X-ray crystallography and cyclic voltammetry.



Producto de Investigación




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