Producción Científica Profesorado

The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}],



Lopez Ruíz, Heraclio

2014

The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}],Gloria Sánchez-Cabrera, Francisco J. Zuno-Cruz, Heraclio López-Ruiz, María J. Rosales-Hoz, Marco A. Leyva y José A. Rodríguez, Journal of Organometallic Chemistry, 751, 826-829, (2014). DOI/10.1016/j.jorganchem.2013.08.035


Abstract


The reaction of the activated cluster [Os3(CO)10(NCMe)2] with 1,3,5-tris(mercaptomethyl)benzene as ligand, gave compound [{Os3(?-H)(CO)10}3{1,3,5-(?-SCH2)3C6H3}], as the sole identifiable product. The cluster has been fully characterized by IR, 1H and 13C NMR spectroscopy, HR-MS, X-ray crystallography and cyclic voltammetry.



Producto de Investigación




Artículos relacionados

Synthesis and Structures of some Lithium and Sodium (Aminoalcoholato)hydrido Aluminates

3-Benzoyl-2-isopropyl-4-alkyloxazolidin-5-ones as Efficient and Inexpensive Sources of Enantiopure ?...

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

A practical access to acyl radicals from acyl hydrazides

Diastereomeric C-glycosyloxanthrones from picramnia antidesma

Phenylboronic acid catalyzed-cyanide promoted, one-pot synthesis of 2-(2-hydroxyphenyl)benzoxazole d...

Synthesis of New Chiral Derivatives of N,N?-Dimethylpropyleneurea (DMPU) and Examination of Their In...

Synthesis, crystal structures, and quadratic nonlinear optical properties in a series of pushpull bo...

Synthesis and Study of Isomeric Benzo[1,4]oxazines and Benzothiazolines by NMR Spectroscopy and X-Ra...

Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes