The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}],
Lopez Ruíz, Heraclio
2014
The synthesis and structural characterization of C3 symmetry ?star-like? cluster [{Os3(m-H)(CO)10}3{1,3,5-(m-SCH2)3C6H3}],Gloria Sánchez-Cabrera, Francisco J. Zuno-Cruz, Heraclio López-Ruiz, María J. Rosales-Hoz, Marco A. Leyva y José A. Rodríguez, Journal of Organometallic Chemistry, 751, 826-829, (2014). DOI/10.1016/j.jorganchem.2013.08.035
Abstract
The reaction of the activated cluster [Os3(CO)10(NCMe)2] with 1,3,5-tris(mercaptomethyl)benzene as ligand, gave compound [{Os3(?-H)(CO)10}3{1,3,5-(?-SCH2)3C6H3}], as the sole identifiable product. The cluster has been fully characterized by IR, 1H and 13C NMR spectroscopy, HR-MS, X-ray crystallography and cyclic voltammetry.
Artículos relacionados
Synthesis of new homochiral 2,3-dialkylpiperazines derived from (R)-(?)-phenylglycinol
Diastereomeric C-glycosyloxanthrones from picramnia antidesma
Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes.
O-benzyl-N-(2-furoyl)thiocarbamate
X-ray crystallographic study of neutral boron chelates with ?-diketones and tropolone