2010
Do Spiroarsoranes Exhibit Polytopal Equilibrium in Solution Antonio R.Tapia-Benavides, Luis H. Mendoza-Huizar, Francisco Pérez-Garca, Hugo Tlahuext, Alejandro Alvarez and Margarita Tlahuextl. Inorg. Chem., 2010, 49 (4), pp 14961502. DOI: 10.1021/ic901740
Abstract
The spiroarsoranes 5-phenyl-1,6-dioxa-4,9-diaza-5?5-arsaspiro[4.4]nonane (6), (3R,8R)-3,8-dimethyl-5-phenyl-1,6-dioxa-4,9-diaza-5?5-arsaspiro[4.4]nonane (7), (2S,7S)-2,7-dimethyl-5-phenyl-1,6-dioxa-4,9-diaza-5?5-arsaspiro[4.4]nonane (8), and (3S,8S)-3,8-dimethyl-(2R,7R)-2,5,7-triphenyl-1,6-dioxa-4,9-diaza-5?5-arsaspiro[4.4]nonane (9) were prepared by reaction of phenylarsonic acid and the correspondig amino alcohol. The presence of polytopal ? ? equilibrium in 6?9 was demonstrated by HPLC and NMR studies. NBO computations at the MP2/6-31+G(2d,2p) level indicate that methyl substitution in C2 or C3 of the oxazarsolane ring determines the predominance of ? or ? stereoisomers. GIAO B3LYP/6-311++G(2d,2p) computations were used to assign experimental 1H and 13C NMR spectra.
The role of temperature in copper electrocrystallization in ammoniachloride solutions
Morphological and magnetic properties of cobalt nanoclusters electrodeposited onto HOPG
A Voltammetric Study Of The Underpotential Deposition Of Cobalt Onto A Glassy Carbon Electrode
Underpotential deposition of cobalt onto polycrystalline platinum