Producción Científica Profesorado

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipyridyl ligands



Galan Vidal, Carlos Andres

2008

Noemí Andrade-López, José G. Alvarado-Rodríguez, Simplicio González-Montiel, Elena Páez-Hernández, Carlos Andrés Galán-Vidal, Araceli Jiménez-Pérez. Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipyridyl ligands. ARKIVOC (2008) v 43-54. ISSN 1424-6376.


Abstract


Coordinative behavior of the di-(2-pyridyl)hydroxymethane (1) and di-(2-pyridyl)-2- pyridylsulfanylmethane (2) ligands towards Pd(II) and Pt(II) is described. The compounds 3-5 were characterized by IR, mass spectrometry and NMR spectroscopy. Crystal structures of [Pt{(C5H4N)2CH(OH)}Cl2] 3 and [Pd{(C5H4N)2CH(2-C5H4NS)}Cl2] 4 as DMSO solvates displayed the formation of neutral mononuclear complexes. In the complexes 3 and 4 is observed the formation of six-membered chelate rings. The local geometry of the metallic atoms can be described as square planar in the title complexes.



Producto de Investigación




Artículos relacionados

Cobalt electrodeposition onto highly oriented pyrolytic graphite (HOPG) electrode from ammonium sulf...

THEORETICAL STUDY ON THE MODIFICATION OF ACTIVE SITES IN GOLD SURFACES MODELED AS FINITE CLUSTERS: I...

Copper Electrodeposition On Glassy Carbon And Highly Oriented Pyrolytic Graphite Substrates From Per...

Influence of the Cation Nature of the Sulphate Salt on the Electrochemical Synthesis of Sulfate-Dope...

Bioacumulación y daños genotóxicos en Pez Cebra (Danio rerio) por arsénico en aguas de Zimapán, Hida...

Chemical Reactivity of Atrazine Employing the Fukui Function

Influence of the Crystallinity of the Substrate on Kinetic Parameters of Zinc Electrodeposition Proc...

Estudio de las Interacciones Ácido Húmico-Metales Pesados y Determinación de sus Constantes de Estab...

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing di...

Mercury Ions Removal from Aqueous Solution Using an Activated Composite Membrane