Producción Científica Profesorado

Organoantimony oxides: preparation and crystal structures of [2-PhOC6H4]O(C6H4)2Sb]2O2 and (o-Tol2Sb)4O6



Alvarado Rodríguez, José Guadalupe

1997

Organoantimony oxides: preparation and crystal structures of [2-PhOC6H4]O(C6H4)2Sb]2O2 and (o-Tol2Sb)4O6. Hans Joachim Breunig, Joachim Probst, Klaus Heinz Ebert, Enno Lork, Raymundo Cea Olivares, José Guadalupe Alvarado Rodríguez Chem. Ber. (1997) 130, 959-61.


Abstract


Air oxidation of (Oxydi-2,1-phenylene)(2-phenoxyphenyl)stibane (1) gives the phenoxystibane oxide [(2-PhOC6H4)O(C6H4)2Sb]2O2 (2). Single crystals of (o-Tol2Sb)4? O4(O2)2 (3) were obtained by air oxidation of o-TolSb-(SiMe3)2. Crystal structures of 2 and 3 are reported.






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