Producción Científica Profesorado

Organoantimony oxides: preparation and crystal structures of [2-PhOC6H4]O(C6H4)2Sb]2O2 and (o-Tol2Sb)4O6



Alvarado Rodríguez, José Guadalupe

1997

Organoantimony oxides: preparation and crystal structures of [2-PhOC6H4]O(C6H4)2Sb]2O2 and (o-Tol2Sb)4O6. Hans Joachim Breunig, Joachim Probst, Klaus Heinz Ebert, Enno Lork, Raymundo Cea Olivares, José Guadalupe Alvarado Rodríguez Chem. Ber. (1997) 130, 959-61.


Abstract


Air oxidation of (Oxydi-2,1-phenylene)(2-phenoxyphenyl)stibane (1) gives the phenoxystibane oxide [(2-PhOC6H4)O(C6H4)2Sb]2O2 (2). Single crystals of (o-Tol2Sb)4? O4(O2)2 (3) were obtained by air oxidation of o-TolSb-(SiMe3)2. Crystal structures of 2 and 3 are reported.





Artículos relacionados

Complexation of the uranyl ion (UO2)2+ with a tetraphenylimidodiphosphinate ligand: the first trinuc...

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipy...

Hypervalence at tin(IV) by transannular bonding of sulfur in an eight-membered ring: The case of dib...

Synthesis and Crystal Structure of [Te{S(C6H3S)2O}]: A Tetracyclic Tellurium(II) Compound Displaying...

Synthesis, Characterisation and Properties of As-Monohalogenated Dibenzoarsocines S(C6H4S)2AsHal (Ha...

Synthesis and Relative Stability of a Series of Compounds of Type [Fe(II)(bztpen)X]+, Where bztpen =...

Pentacoordination at Germanium by Transannular Bonding of Sulfur or Oxygen in an Eight-Membered Ring...

Structural Studies by NMR and X-Ray Crystallography of N-(p-Toluenesulfonyl)-Amino Acids

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

Pentacoordination at antimony in dibenzostibocines via DSb transannular interactions (D = O, S): A s...