Producción Científica Profesorado

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2



Alvarado Rodríguez, José Guadalupe

2010

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2. Francisco Pérez-García, José G. Alvarado-Rodríguez, Carlos Andrés. Galán-Vidal, María Elena. Páez-Hernández, , Noemí Andrade-López, Rafael Moreno-Esparza, Struct. Chem., 21 (2010) 191-196. ISSN: 1040-0400 (print version) ISSN: 1572-9001 (electronic version) DOI: 10.1007/s11224-009-9562-5


Abstract


Treatment of KS2P(OC6H4)2 (1) with five n-alkyl halides afforded the stable n-alkyldithiophosphate compounds RS2P(OC6H4)2 (26). Single crystal X-ray analysis revealed that the PS2 fragment in 1 displays an isobidentate coordination pattern; compounds 24 display a monodentate binding pattern. The crystal packing of title compounds is stabilized by cation-?, weak hydrogen bonding CH---O, as well as aromatic non-bonded interactions.



Producto de Investigación




Artículos relacionados

Ni(II) and Pd(II) organometallic and coordination complexes with a new tridentate N,N,O-donor ligand...

Mild Oxidation of C?C Bonds of Benzoiridacycles

Synthesis, characterization and crystal structures of dipyridyl-N-methylimine and cloro-bis (N,N?-2,...

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2

Structural Studies by NMR and X-Ray Crystallography of N-(p-Toluenesulfonyl)-Amino Acids

Hypervalence at tin(IV) by transannular bonding of sulfur in an eight-membered ring: The case of dib...

Hypervalence in germanium compounds containing the tetracylic moiety {S(C6H3S)2O}Ge via OGe transann...

Pentacoordination at antimony in dibenzostibocines via DSb transannular interactions (D = O, S): A s...

Six-membered ring chelate complexes of Pd(II) and Pt(II) derived from di-(2-pyridyl)pyrimidin-2-ylsu...

Synthesis, Characterisation and Properties of As-Monohalogenated Dibenzoarsocines S(C6H4S)2AsHal (Ha...