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Synthesis and Crystal Structure of [Te{S(C6H3S)2O}]: A Tetracyclic Tellurium(II) Compound Displaying a BoatChair Conformation

Alvarado Rodríguez, José Guadalupe


Synthesis and crystal structure of [Te{S(C6H3S)2O}]: A tetracylcic tellurium(II) compound displaying and boat-chair conformation. Diego Martínez-Otero, José G. Alvarado-Rodríguez, Noemí Andrade-López, Journal of Chemical Crystallography, 2010, 40, 531-535. ISSN: 1074-1542 (print version) ISSN: 1572-8854 (electronic version). DOI: 10.1007/s10870-010-9691-0


The synthesis and molecular structure of (phenoxathiin-4,6-dithiolate)tellurium(II) is described. [Te{S(C6H3S)2O}] was synthesized from the reaction of 4,6-dimercaptophenoxatiin and TeCl4 in 36% yield. The crystal structure was determined by single crystal X-ray diffraction analysis. Crystal data: [Te{S(C6H3S)2O}], formula weight = 389.95, crystallized in monoclinic system, space group P2(1)/n with a = 7.7898(10) Å, b = 18.513(2) Å, c = 8.9898(11) Å, ? = 105.974(2), V = 1246.4(3) Å3 and Z = 4. The tetracyclic compound is non-planar with a di-coordinate TeII atom. The eight-membered central ring is in a boatchair conformation. The title compound displays weak intermolecular contacts TeS, SS and CH?S.

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