Producción Científica Profesorado

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)



Alvarez Hernandez, Alejandro

2004

Horacio Vásquez-Arciga, Aarón Pérez-Benítez, Alejandro Álvarez Hernández, Sylvain Bernesd and Miguel Ángel Méndez-Rojas. Bis(acetylsalicylato-k2O,O)diaquacadmium(II). Acta Crystallographica Section E Structure Reports. 2004, E60, m1621-m1623. ISSN 1600-5368. Reino Unido.


Abstract


In the title compound {systematic name: bis[2-(acetyloxy) benzoato-_2O,O0]diaquacadmium(II)}, [Cd(C9H7O4)2- (H2O)2], the CdII ion is located on a twofold rotation axis and is coordinated by two water molecules and two aspirinate ligands. The complex is almost isostructural with the corresponding zinc(II) complex. However, for the title compound, the aspirinate should be considered as an asymmetric chelating ligand, with CdÐO(carboxylate) bond lengths of 2.2777 (12) and 2.4121 (12) A Ê .



Producto de Investigación




Artículos relacionados

New boronates prepared from 2,4-pentanedione derived ligands of the NO2 and N2O2 type comparison to...

Further insight into three center hydrogen bonding. Participation in tautomeric equilibria of hetero...

Highly diastereoselective alkylation, acylation and aldol condensation of cis- and trans-(N-acyloyl)...

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reactio

O-benzyl-N-(2-furoyl)thiocarbamate

3-Benzoyl-2-isopropyl-4-alkyloxazolidin-5-ones as Efficient and Inexpensive Sources of Enantiopure ?...

Structure-Activity Relationships for Inhibition of Cysteine Protease Activity and Development of Pla...

Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles

Furocoumarins of three species of the genus Dorstenia

Synthesis, crystal structures, and quadratic nonlinear optical properties in a series of pushpull bo...