Producción Científica Profesorado

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)



Alvarez Hernandez, Alejandro

2004

Horacio Vásquez-Arciga, Aarón Pérez-Benítez, Alejandro Álvarez Hernández, Sylvain Bernesd and Miguel Ángel Méndez-Rojas. Bis(acetylsalicylato-k2O,O)diaquacadmium(II). Acta Crystallographica Section E Structure Reports. 2004, E60, m1621-m1623. ISSN 1600-5368. Reino Unido.


Abstract


In the title compound {systematic name: bis[2-(acetyloxy) benzoato-_2O,O0]diaquacadmium(II)}, [Cd(C9H7O4)2- (H2O)2], the CdII ion is located on a twofold rotation axis and is coordinated by two water molecules and two aspirinate ligands. The complex is almost isostructural with the corresponding zinc(II) complex. However, for the title compound, the aspirinate should be considered as an asymmetric chelating ligand, with CdÐO(carboxylate) bond lengths of 2.2777 (12) and 2.4121 (12) A Ê .



Producto de Investigación




Artículos relacionados

Highly diastereoselective alkylation, acylation and aldol condensation of cis- and trans-(N-acyloyl)...

Preparation of N-aryl-substituted spiro-?-lactams via Staudinger cycloaddition

Synthesis and Study of Monomeric and Dimeric Boronates by Spectroscopic Methods and X-ray Crystallog...

Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles

Synthesis, crystal structures, and quadratic nonlinear optical properties in a series of pushpull bo...

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

Synthesis of nitrogen-, oxygen- and sulphur-containing tripodal ligands with a trimethylbenzene core...

Phenylboronic acid catalyzed-cyanide promoted, one-pot synthesis of 2-(2-hydroxyphenyl)benzoxazole d...

X-ray crystallographic study of neutral boron chelates with ?-diketones and tropolone

Synthesis of New Chiral Derivatives of N,N?-Dimethylpropyleneurea (DMPU) and Examination of Their In...