Producción Científica Profesorado

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)



Alvarez Hernandez, Alejandro

2004

Horacio Vásquez-Arciga, Aarón Pérez-Benítez, Alejandro Álvarez Hernández, Sylvain Bernesd and Miguel Ángel Méndez-Rojas. Bis(acetylsalicylato-k2O,O)diaquacadmium(II). Acta Crystallographica Section E Structure Reports. 2004, E60, m1621-m1623. ISSN 1600-5368. Reino Unido.


Abstract


In the title compound {systematic name: bis[2-(acetyloxy) benzoato-_2O,O0]diaquacadmium(II)}, [Cd(C9H7O4)2- (H2O)2], the CdII ion is located on a twofold rotation axis and is coordinated by two water molecules and two aspirinate ligands. The complex is almost isostructural with the corresponding zinc(II) complex. However, for the title compound, the aspirinate should be considered as an asymmetric chelating ligand, with CdÐO(carboxylate) bond lengths of 2.2777 (12) and 2.4121 (12) A Ê .



Producto de Investigación




Artículos relacionados

Further insight into three center hydrogen bonding. Participation in tautomeric equilibria of hetero...

A practical access to acyl radicals from acyl hydrazides

Structure-Activity Relationships for Inhibition of Cysteine Protease Activity and Development of Pla...

Diastereomeric C-glycosyloxanthrones from picramnia antidesma

X-ray crystallographic study of neutral boron chelates with ?-diketones and tropolone

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

Ylidaddukte der Penteltrichloride

Structural studies of spiroarsoranes derived from 2-aminophenols

Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles

Synthesis of new homochiral 2,3-dialkylpiperazines derived from (R)-(?)-phenylglycinol