Producción Científica Profesorado

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)



Alvarez Hernandez, Alejandro

2004

Horacio Vásquez-Arciga, Aarón Pérez-Benítez, Alejandro Álvarez Hernández, Sylvain Bernesd and Miguel Ángel Méndez-Rojas. Bis(acetylsalicylato-k2O,O)diaquacadmium(II). Acta Crystallographica Section E Structure Reports. 2004, E60, m1621-m1623. ISSN 1600-5368. Reino Unido.


Abstract


In the title compound {systematic name: bis[2-(acetyloxy) benzoato-_2O,O0]diaquacadmium(II)}, [Cd(C9H7O4)2- (H2O)2], the CdII ion is located on a twofold rotation axis and is coordinated by two water molecules and two aspirinate ligands. The complex is almost isostructural with the corresponding zinc(II) complex. However, for the title compound, the aspirinate should be considered as an asymmetric chelating ligand, with CdÐO(carboxylate) bond lengths of 2.2777 (12) and 2.4121 (12) A Ê .



Producto de Investigación




Artículos relacionados

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reaction

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

Addition reaction of benzylbenzylidenenamine to lithium enolates of 1,3-dioxolan-4-one: synthesis of...

3-Benzoyl-2-isopropyl-4-alkyloxazolidin-5-ones as Efficient and Inexpensive Sources of Enantiopure ?...

A practical access to acyl radicals from acyl hydrazides

Further insight into three center hydrogen bonding. Participation in tautomeric equilibria of hetero...

X-ray crystallographic study of neutral boron chelates with ?-diketones and tropolone

Structure-Activity Relationships for Inhibition of Cysteine Protease Activity and Development of Pla...

Preparation of N-aryl-substituted spiro-?-lactams via Staudinger cycloaddition

Synthesis and Structures of some Lithium and Sodium (Aminoalcoholato)hydrido Aluminates