Producción Científica Profesorado

Estudio estructural de interacciones intra- e intermoleculares basadas en puentes de hidrógeno en piridin-2,6-dicarboxamidas.



Andrade López, Noemí

2018

Estudio estructural de interacciones intra- e intermoleculares basadas en puentes de hidrógeno en piridin-2,6-dicarboxamidas. Noemí Andrade-López*, José G. Alvarado-Rodríguez, J. Roberto Pioquinto-Mendoza Pädi. Boletín Científico de Ciencias Básicas e Ingeniería. 10(2018) 9-13. https://doi.org/10.29057/icbi.v5i10


Abstract


Study of hydrogen bonding in pyridine-2,6-dicarboxamidesof general formula {(2,6-CONRH)2(C5H3N)} [R = H (1); R =CH3 (2); R = CH2CH3 (3); R = 2-Br-C6H4 (4); R = CH2(2-C5H4N) (5)] by NMR and infrared is described. Intermolecularinteractions of types NHOH2, NHOC and NHOSMe2,and intramolecular NHN interactions for the amides 1-5 inAndrade-López N. et al. / Publicación Semestral Pädi No. 10 (2018) 9?13 12solution and solid state were established. In 1-5, the intramolecular hydrogen bonds formed with the hydrogen atoms of the NH amidic group and the pyridinic nitrogen (NHN) yielded the formation of five membered rings. The hydrogen bonds in these compounds enhance the amide form as the main tautomer associated to their structure.



Producto de Investigación UAEH




Artículos relacionados

Synthesis, characterization and crystal structures of organolead dithiolate compounds displaying tra...

Synthesis, characterization and crystal structures of dipyridyl-N-methylimine and cloro-bis (N,N?-2,...

Understanding and Predicting Distorted T- versus Y-Geometries for Neutral Chromous Complexes Support...

Synthesis, characterization and crystal structures of organolead dithiolate compounds displaying tra...

Five-membered ring chelate complexes of Ni(II), Pd(II) and Pt(II) derived of di-(2-pyridyl)-N-ethyli...

Boron heterocycles derived from 2-guanidinobenzimidazole

Pentacoordination at antimony in dibenzostibocines via DSb transannular interactions (D = O, S): A s...

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

Study of the D?Sb (D = O, S) Transannular Interaction in Sb-Monohalogenated Dibenzostibocines ? An E...