Expedient synthesis of highly functionalized abnormal gold complexes.
Alvarez Hernandez, Alejandro
2018
Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.
Abstract
The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups
Artículos relacionados
Furocoumarins of three species of the genus Dorstenia
Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles
The Structural Chemistry of N-Monolithium Borazines
Diastereomeric C-glycosyloxanthrones from picramnia antidesma
A flexible access to highly functionalised boronates
Synthesis of new homochiral 2,3-dialkylpiperazines derived from (R)-(?)-phenylglycinol
Structural studies of spiroarsoranes derived from 2-aminophenols