Producción Científica Profesorado

Expedient synthesis of highly functionalized abnormal gold complexes.



Alvarez Hernandez, Alejandro

2018

Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.


Abstract


The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups



Producto de Investigación




Artículos relacionados

Furocoumarins of three species of the genus Dorstenia

Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes.

Phenylmethyl 2,3,4-tri-O-acetyl--D-fucopyranoside

Enantioselective synthesis of ?-amino acids. Part 11: Diastereoselective alkylation of chiral deriva...

Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes

X-ray crystallographic study of neutral boron chelates with ?-diketones and tropolone

Effect of TiO2Al2O3 SolGel Supports on the Superficial Ni and Mo Species in Oxidized and Sulfided Ni...

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reaction

Study of the reactivity of squarylferrocenes. Addition of amines and aminoesters

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.