2012
Ung, G.; Mendoza-Espinosa, D.; Bertrand G. Novel Route to Ynamides: Stable Ligands Equivalent to Unstable Oxazol-4-Ylidenes. Chem. Commun. 2012, 48, 7088-7090.
Abstract
Deprotonation of an oxazolium salt induces a ring opening process leading to the corresponding ynamide. Although the expected mesoionic carbene is not obtained, the acyclic ynamide readily reacts with various transition metals yielding robust mesoionic carbene complexes.
Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling
First Total Synthesis of ()-Flustraminol B
Synthesis of 6-bromo-2-arylindoles using 2-iodobenzoic acid as precursor
One-potsynthesis of conformationallyrestrictedspirooxindoles
Aromatic Bromination versus Oxidation of Indolylmalonates by Bromine
Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters