Producción Científica Profesorado

Mesoionic Thiazol-5-ylidenes as Ligands for Transition Metal Complexes.



Mendoza Espinosa, Daniel

2011

Mendoza-Espinosa, D.; Ung, G. Donnadieu, B.; Bertrand, G. Mesoionic Thiazol-5-ylidenes as Ligands for Transition Metal Complexes. Chem. Commun. 2011, 47, 10614-10616.


Abstract


The first examples of thiazol-5-ylidene complexes featuring group 9, 10 and 11 metal centers, have been prepared by deprotonation of a series of 2,3,4-triaryl-susbtituted thiazolium salts in the presence of the corresponding transition metal precursor.






Artículos relacionados

Synthesis of Bromoindole Alkaloids from Laurencia brongniartii

The absoluteconfiguration of cuauhtemone and related compounds

Synthesis of Acetamido(indol-3-yl)propanol Derivatives

13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters

Trapping enols of esters and lactones with diazomethane

Preparation of 3-hydroxyoxindoles with dimethyldioxirane and their use for the synthesis of natural ...

Cascade [1,3]-Sigmatropic Rearrangements of Ketene O,O-Acetals: Kinetic and DFT Level Mechanistic St...

One-potsynthesis of conformationallyrestrictedspirooxindoles

Firsttotalsyntheses of dihydroflustramine C and flustramine E, alkaloids from the marine bryozoan Fl...

Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase