Producción Científica Profesorado

Mesoionic Thiazol-5-ylidenes as Ligands for Transition Metal Complexes.



Mendoza Espinosa, Daniel

2011

Mendoza-Espinosa, D.; Ung, G. Donnadieu, B.; Bertrand, G. Mesoionic Thiazol-5-ylidenes as Ligands for Transition Metal Complexes. Chem. Commun. 2011, 47, 10614-10616.


Abstract


The first examples of thiazol-5-ylidene complexes featuring group 9, 10 and 11 metal centers, have been prepared by deprotonation of a series of 2,3,4-triaryl-susbtituted thiazolium salts in the presence of the corresponding transition metal precursor.






Artículos relacionados

Cascade [1,3]-Sigmatropic Rearrangements of Ketene O,O-Acetals: Kinetic and DFT Level Mechanistic St...

One-potsynthesis of conformationallyrestrictedspirooxindoles

Total Syntheses of Five Indole Alkaloids from the Marine Bryozoan Flustra foliacea

Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling

First Total Synthesis of ()-Flustraminol B

Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase

Synthesis of 6-bromo-2-arylindoles using 2-iodobenzoic acid as precursor

Conformationalstudies of N-carbomethoxy-2-alkoxyindolenines by dynamic NMR, crystallography, and mol...

Cleavage of alkoxycarbonyl protecting groups from carbamates by t-BuNH2

Preparation of 3-hydroxyoxindoles with dimethyldioxirane and their use for the synthesis of natural ...