Producción Científica Profesorado

Mesoionic Thiazol-5-ylidenes as Ligands for Transition Metal Complexes.



Mendoza Espinosa, Daniel

2011

Mendoza-Espinosa, D.; Ung, G. Donnadieu, B.; Bertrand, G. Mesoionic Thiazol-5-ylidenes as Ligands for Transition Metal Complexes. Chem. Commun. 2011, 47, 10614-10616.


Abstract


The first examples of thiazol-5-ylidene complexes featuring group 9, 10 and 11 metal centers, have been prepared by deprotonation of a series of 2,3,4-triaryl-susbtituted thiazolium salts in the presence of the corresponding transition metal precursor.






Artículos relacionados

Cleavage of alkoxycarbonyl protecting groups from carbamates by t-BuNH2

Conformationalstudies of N-carbomethoxy-2-alkoxyindolenines by dynamic NMR, crystallography, and mol...

Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase

Regioselective Synthesis of 3-Indolyl(alkoxy)acetates

Firsttotalsyntheses of dihydroflustramine C and flustramine E, alkaloids from the marine bryozoan Fl...

Synthesis of ?4:?2-Exocyclic-Diene Iridium(I) Complexes Derived from 1,3-Oxazolidin-2-ones and Their...

Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives

Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles

Trapping enols of esters and lactones with diazomethane

Stereochemical assignment of naturally occurring 2,3-epoxy-2-methylbutanoate esters