2017
Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexeswith a C4-Symmetric Tetratriazol-5-ylideneMariana Flores-Jarillo, Daniel Mendoza-Espinosa,* Verónica Salazar-Pereda, Simplicio González-Montiel, Organometallics, 2017doi:10.1021/acs.organomet.7b00712
Abstract
The facile preparation of a C4-symmteric tetratriazolium salt and its subsequent metalation to generate a series of tetranuclear mesoionic carbene gold(I) complexes is presented. The complete structural characterization of the metallic carbenes and the benefits of cooperative catalysis in the processes of hydroamination and hydrohydrazination of terminal alkynes are discussed.
Trapping enols of esters and lactones with diazomethane
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters
The absoluteconfiguration of cuauhtemone and related compounds
Aromatic Bromination versus Oxidation of Indolylmalonates by Bromine
Stereochemical assignment of naturally occurring 2,3-epoxy-2-methylbutanoate esters
Regioselective Synthesis of 3-Indolyl(alkoxy)acetates
Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling
Synthesis of 6-bromo-2-arylindoles using 2-iodobenzoic acid as precursor