2017
Visible-Light-Promoted AuI to AuIII Oxidation in Triazol-5-ylidene Complexes, Daniel Mendoza-Espinosa, David Rendon-Nava, Alejandro Alvarez-Hernandez, Deyanira Angeles-Beltran, Guillermo E. Negron-Silva, and Oscar R. Suarez-Castillo, Chem. Asian J. 2017, 12, 203 - 207
Abstract
Reaction of triazolium precursors [MIC(CH2)n? H+]I? (n=1?3) with potassium hexamethyldisilazane (KHMDS) and AuCl(SMe2) generates the gold(I) complexes of the type MIC(CH2)n?AuI. Visible light exposure of the latter complexes promotes a spontaneous disproportionation process rendering gold(III) complexes of the type [{MIC(CH2)n}2?AuI2]+I?. Both the AuI and AuIII complex series were tested in the catalytic hydrohydrazination of terminal alkynes using hydrazine as nitrogen source.
One-potsynthesis of conformationallyrestrictedspirooxindoles
Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives
Transesterifications mediated by t-BuNH2
Total Syntheses of Five Indole Alkaloids from the Marine Bryozoan Flustra foliacea
Synthesis of Acetamido(indol-3-yl)propanol Derivatives
Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles
The absoluteconfiguration of cuauhtemone and related compounds
Aromatic Bromination versus Oxidation of Indolylmalonates by Bromine
Role of lipid peroxidation in biliary obstruction in the rat
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters