Producción Científica Profesorado

Quantification of As(III) by Swasv on Glassy Carbon Electrode Codeposit Copper with Presence of B-Ciclodextrin



Mendoza Huizar, Luis Humberto

2013

López-Vargas, E., Galán-Vidal, C.A., Rodríguez-Ávila, J.A., Álvarez-Romero, G.A. Mendoza-Huizar, L.H. ECS Trans.. 2013, 47(1), 131-136.


Abstract


Nowadays, the ability to detect arsenic in drinking water is a very important subject because of arsenic's toxicity. In this sense, it is necessary to have economical and portable detection methodologies in order to control water quality, mainly in remote communities without access to expensive equipment such as atomic absorption. Currently, electrochemical methods are a low cost alternative which can be used outside the laboratory; however, these techniques use toxic or precious metals as working electrodes. The main interference in the quantification of arsenic is the Cu(II) because an intermetallic compound is formed with arsenic. In this paper we explore the co-deposition of Cu on a glassy carbon electrode to quantify As(III) in H2SO4 as a supporting electrolyte. The methodology reported a detection limit of 5.2 ?g L-1, helpful to following the official guidelines. Zn2+, Fe2+, Pb2+, Hg2+ and Cl- are not significant interferences in quantification.



Producto de Investigación




Artículos relacionados

Underpotential deposition of cobalt onto polycrystalline platinum

Nucleation and growth of cobalt onto different substrates: Part II. The upd-opd transition onto a go...

Bioacumulación y daños genotóxicos en Pez Cebra (Danio rerio) por arsénico en aguas de Zimapán, Hida...

Magnetic transition phase diagram of cobalt clusters electrodeposited on HOPG: Experimental and micr...

Nucleation and growth of cobalt onto different substrates: Part I. Underpotential deposition onto a ...

Cobalt Electrodeposition Process from Electrolytic Baths based on CoSO4 and (NH4)2SO4. Influence of ...

Characterization of Main Anthocyanins Extracted from Pericarp Blue Corn by MALDI-ToF MS

Revisión de variables de diseño y condiciones de operación en la electrocoagulación

Nucleation and Growth Kinetics of Electrodeposited Sulfate-Doped Polypyrrole: Determination of the D...

Kinetic study of the cobalt electrodeposition onto glassy carbon electrode from ammonium sulfate sol...