Producción Científica Profesorado

trans-Bis[2-(aminomethyl)-1H-benzimidazole-2N2,N3]aquacopper(II) dichloride dihydrate



Tapia Benavides, Antonio Rafael

2007

Hugo Tlahuext, Margarita Tlahuextl, Sandra López-Gámez, Antonio R Tapia-Benavides*, Trans-bis[2-(aminomethyl)-1H-bencimidazole-k2N2,N3]aquacopper(II) dichloride dihydrate, Acta Crystallographica E, E63, m1263-m1265 (2007). DOI: http://dx.doi.org/10.1107/S1600536807002772


Abstract


In the title compound, [Cu(C8H9N3)2(H2O)]Cl22H2O, the CuII ion is coordinated in a square-pyramidal geometry, with four N atoms as basal ligands and one water O atom as an apical ligand. The complex molecule is situated on a crystallographic twofold rotation axis. The molecules are bonded to their neighbours by N-HO, O-HCl and N-HCl hydogen bonds. The packing is further stabilized by - interactions between the substituted imidazole molecules.



Producto de Investigación




Artículos relacionados

Synthesis of Zn compounds derived from 1H-benzimidazol-2-ylmethanamine

SYNTHESES, NMR STUDY AND STEREOCHEMISTRY OF NEW P-H TRICYCLOPHOSPHORANES

Three-center intramolecular hydrogen bonding in oxamide derivatives. NMR and X-ray diffraction study

1 H, 13C, 15N, 2D and variable temperature NMR study of the role of hydrogen bonding in the structur...

Chlorination reactions of ephedrines revisited. Stereochemistry and functional groups effect on the ...

Synthesis and structural studies of new N-(p-toluenesulfonyl)amino acid o-phenolamides

New 3,3?[2,2?-oxy-bis-(oxazaborolidine)]-ethylenes. Structural studies by NMR, X-ray, and quantum ch...

Acid-base equilibrium studies of 2-(aminomethyl)benzimidazolein aqueous solution

Addition reactions of protonic reagents to optically active 2-phenyl-1,3,2-oxazaborolines

Synthesis and structural studies of N-(p-toluenesulfonyl)-amino acid 3,5-di-tert-butyl-2-phenolamide...