Producción Científica Profesorado

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2



Alvarado Rodríguez, José Guadalupe

2010

Synthesis, characterization, and crystal structures of n-alkyldiorganodithiophosphates RS2P(OC6H4)2. Francisco Pérez-García, José G. Alvarado-Rodríguez, Carlos Andrés. Galán-Vidal, María Elena. Páez-Hernández, , Noemí Andrade-López, Rafael Moreno-Esparza, Struct. Chem., 21 (2010) 191-196. ISSN: 1040-0400 (print version) ISSN: 1572-9001 (electronic version) DOI: 10.1007/s11224-009-9562-5


Abstract


Treatment of KS2P(OC6H4)2 (1) with five n-alkyl halides afforded the stable n-alkyldithiophosphate compounds RS2P(OC6H4)2 (26). Single crystal X-ray analysis revealed that the PS2 fragment in 1 displays an isobidentate coordination pattern; compounds 24 display a monodentate binding pattern. The crystal packing of title compounds is stabilized by cation-?, weak hydrogen bonding CH---O, as well as aromatic non-bonded interactions.



Producto de Investigación




Artículos relacionados

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

Pyrite?Arsenopyrite Galvanic Interaction and Electrochemical Reactivity

Study of the D?Sb (D = O, S) Transannular Interaction in Sb-Monohalogenated Dibenzostibocines ? An E...

Pentacoordination at antimony in dibenzostibocines via DSb transannular interactions (D = O, S): A s...

Synthesis and Crystal Structure of [Te{S(C6H3S)2O}]: A Tetracyclic Tellurium(II) Compound Displaying...

Structural Studies by NMR and X-Ray Crystallography of N-(p-Toluenesulfonyl)-Amino Acids

Synthesis and Spectroelectrochemical Studies of Mixed Heteroleptic Chelate Complexes of Ruthenium(II...

Mild Oxidation of C?C Bonds of Benzoiridacycles

Synthesis, characterization and crystal structures of dipyridyl-N-methylimine and cloro-bis (N,N?-2,...

Study on the intramolecular transannular chalcogentin interactions in dithiastannecine compounds.