Producción Científica Profesorado

Organoantimony oxides: preparation and crystal structures of [2-PhOC6H4]O(C6H4)2Sb]2O2 and (o-Tol2Sb)4O6



Alvarado Rodríguez, José Guadalupe

1997

Organoantimony oxides: preparation and crystal structures of [2-PhOC6H4]O(C6H4)2Sb]2O2 and (o-Tol2Sb)4O6. Hans Joachim Breunig, Joachim Probst, Klaus Heinz Ebert, Enno Lork, Raymundo Cea Olivares, José Guadalupe Alvarado Rodríguez Chem. Ber. (1997) 130, 959-61.


Abstract


Air oxidation of (Oxydi-2,1-phenylene)(2-phenoxyphenyl)stibane (1) gives the phenoxystibane oxide [(2-PhOC6H4)O(C6H4)2Sb]2O2 (2). Single crystals of (o-Tol2Sb)4? O4(O2)2 (3) were obtained by air oxidation of o-TolSb-(SiMe3)2. Crystal structures of 2 and 3 are reported.





Artículos relacionados

Complexation of the uranyl ion (UO2)2+ with a tetraphenylimidodiphosphinate ligand: the first trinuc...

Study on the intramolecular transannular chalcogentin interactions in dithiastannecine compounds.

Synthesis, characterization and crystal structures of organolead dithiolate compounds displaying tra...

Pyrite?Arsenopyrite Galvanic Interaction and Electrochemical Reactivity

Synthesis, Characterisation and Properties of As-Monohalogenated Dibenzoarsocines S(C6H4S)2AsHal (Ha...

Hypervalence at tin(IV) by transannular bonding of sulfur in an eight-membered ring: The case of dib...

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

Hypervalence in germanium compounds containing the tetracylic moiety {S(C6H3S)2O}Ge via OGe transann...

Study of the D?Sb (D = O, S) Transannular Interaction in Sb-Monohalogenated Dibenzostibocines ? An E...

Synthesis and Spectroelectrochemical Studies of Mixed Heteroleptic Chelate Complexes of Ruthenium(II...