Producción Científica Profesorado

Electrochemical and AFM characterization of the electropolimerization of pyrrole over a graphiteepoxy resin solid composite electrode, in the presence of different anions



Galan Vidal, Carlos Andres

2006

G.A. Álvarez-Romero, E. Garfias-García, M.T. Ramírez-Silva, C. Galán-Vidal, M. Romero-Romo and M. Palomar-Pardavé. Electrochemical and AFM characterization of the electropolimerization of pyrrole over a graphite-epoxy resin solid composite electrode, in the presence of different anions. Applied Surface Science 252 (2006) 5783-5792. ISSN 0169-4332


Abstract


his work studied the process of electrochemical formation of polypyrrole, Ppy, over a graphiteepoxy resin composite electrode in the presence of different anions: DS?, NO3? and Cl?. It was shown by means of AFM that the morphological characteristics and the formation kinetics of the Ppy deposit, from analysis of experimental current density transients, are strongly dependent on the nature of the anion present. It was found that for all cases, the formation mechanism involves the simultaneous presence of adsorption and 3D nucleation, limited by diffusion of the different pyrrole oligomer species, processes.






Artículos relacionados

Nucleation and Growth Kinetics of Electrodeposited Sulfate-Doped Polypyrrole: Determination of the D...

Magnetic transition phase diagram of cobalt clusters electrodeposited on HOPG: Experimental and micr...

Nucleation and Growth Kinetics of Electrodeposited Sulfate-Doped Polypyrrole: Determination of the D...

Characterization of Main Anthocyanins Extracted from Pericarp Blue Corn by MALDI-ToF MS

Kinetics of Polypyrrole Films Doped with Sulphate Ions Electrodeposited Over Graphite - Epoxy Resin ...

Influence of the Cation Nature of the Sulphate Salt on the Electrochemical Synthesis of Sulfate-Dope...

Mercury Ions Removal from Aqueous Solution Using an Activated Composite Membrane

Influence of the Crystallinity of the Substrate on Kinetic Parameters of Zinc Electrodeposition Proc...

Do Spiroarsoranes Exhibit Polytopal Equilibrium in Solution?

Revisión de variables de diseño y condiciones de operación en la electrocoagulación