Producción Científica Profesorado

Electrochemical Determination of Pb(II) Using Carbon Paste Electrodes Modified with Ion Imprinted Polymers (IIPs).

Galan Vidal, Carlos Andres


Luz E. Rebolledo, Giaan Arturo Álvarez Romero, Israel Samuel Ibarra-Ortega, Carlos Andres Galan-Vidal, Irma Pérez-Silva. (2022). Electrochemical Determination of Pb(II) Using Carbon Paste Electrodes Modified with Ion Imprinted Polymers (IIPs). ECS Transactions, 106, 21.


An easy, low-cost, and highly selective carbon paste electrode based on an ion-imprinted polymer (IIP) to determine Pb(II) in real samples was developed. The recognition cavities based on a cross-linked polymer selective to Pb(II) were created using vinyl pyridine. The modified CPE was constructed by a composite mixture with the synthesized IIP. A notable difference was observed in the electrochemical response of the electrodes modified with the IIP and a non-imprinted polymer, demonstrating the unique properties of the IIP recognition sites. The parameters related to the current intensity were optimized; the selectivity was also studied considering potential interference ions. The proposed modified electrode demonstrated to be as (or more) selective to Pb(II) compared to others previously reported in the literature. A linear concentration range from 3.3 mg/L to 33 mg/L with a limit detection of 1 mg/L was obtained. The Pb(II) preconcentrated on the electrode surface was successfully quantified in real potable water samples without previous treatment.

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