2019
Gelacio Martínez-Gudiño, Nadia A.Pérez-Rojas, Joel J.Trujillo-Serrato, Yolanda Mora-Pérez, Oscar R.Suárez-Castillo, Martha S.Morales-Ríos, Journal of Molecular Structure, 1175 (2019) 828-835 doi:10.1016/j.molstruc.2018.08.056
Abstract
An eco-friendly equilibrated rearrangement of a series of 2-oxo-3-indolyl acetic acids (1) with 2-oxo-1,2,3,4-tetrahydroquinoline-4-carboxylic acid derivatives (2) was investigated through a solid state melt reaction (SSMR). Mechanistic insight into the thermal rearrangement is provided by 13C-isotopic labeling. The standard mass spectra of 1 and 2 were virtually identical preventing their reliable identification. Reversible interconversion of 1 and 2 was evidenced to occur in the inlet system of a mass spectrometer under electron impact conditions. Relative abundances of fragment ions were found to be a function of temperature.
Regioselective Synthesis of 3-Indolyl(alkoxy)acetates
Trapping enols of esters and lactones with diazomethane
Stereochemical assignment of naturally occurring 2,3-epoxy-2-methylbutanoate esters
Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling
The absoluteconfiguration of cuauhtemone and related compounds
Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase