Producción Científica Profesorado

Electrochemical Study of the Pd electrodeposition on Glassy Carbon Electrode fromammoniacal solutions at basic and acid pH values.



Mendoza Huizar, Luis Humberto

2017

A. S. Bravo-Rodriguez, , L.H. Mendoza-Huizar, ECS Transactions, 2017, 76 (1), 29-35doi: 10.1149/07601.0029ecst


Abstract


In the present work, it was analyzed the Pd electrodeposition from the system GCE/0.001M PdCl2 + 1M NH4Cl, at pH=5 and 8, through cyclic voltammetry and chronoamperometry techniques, in different temperatures. The analysis of the potentiostatic transients suggests the presence of a progressive nucleation and growth process. By means of nonlinear fittings of the experimental transients to the nucleation and growth model proposed by Palomar Pardavé et al, it was possible to calculate the values of the diffusion coefficient, nucleation rate and the number of the active nucleation sites. All these parameters were potential dependent in both pH solutions



Producto de Investigación




Artículos relacionados

A Voltammetric Study Of The Underpotential Deposition Of Cobalt Onto A Glassy Carbon Electrode

Characterization of Main Anthocyanins Extracted from Pericarp Blue Corn by MALDI-ToF MS

ELECTROCHEMICAL STUDY ABOUT ZINC ELECTRODEPOSITION ONTO GCE AND HOPG SUBSTRATES

Do Spiroarsoranes Exhibit Polytopal Equilibrium in Solution?

Influence of the Crystallinity of the Substrate on Kinetic Parameters of Zinc Electrodeposition Proc...

Quantum chemical study of the electrochemical reduction of the [Co(H2O)6]2+ and [Co(NH3)5(H2O)]2+ io...

Efecto de la composición del soporte sobre las estructuras superficiales de óxidos de níquel y molib...

Copper Electrodeposition On Glassy Carbon And Highly Oriented Pyrolytic Graphite Substrates From Per...

Cobalt Electrodeposition Process from Electrolytic Baths based on CoSO4 and (NH4)2SO4. Influence of ...

Nucleation and Growth Kinetics of Electrodeposited Sulfate-Doped Polypyrrole: Determination of the D...