Producción Científica Profesorado

Hydrogenation of imines catalysed by ruthenium(II) complexes based on lutidine-derived CNC pincer ligands



Salazar Pereda, Verónica

2013

Hernandez-Juarez, M; Vaquero, M; Alvarez, E; Salazar, V ; Suarez, A., Hydrogenation of imines catalysed by ruthenium(II) complexes based on lutidine-derived CNC pincer ligands, DALTON TRANSACTIONS, Año: 2013 Volume: 42 Issue: 2 Pages: 351-354 DOI: 10.1039/c2dt31907a ISSN: 1477-9226


Abstract


The preparation of new Ru(II) complexes incorporating fac-coordinated lutidine-derived CNC ligands is reported. These derivatives are selectively deprotonated by tBuOK at one of the methylene arms of the pincer, leading to catalytically active species in the hydrogenation of imines.



Producto de Investigación




Artículos relacionados

Reactivity of Triosmium Carbonyl Clusters with 1,8-Diaminonaphthalene ? Synthesis and Structural Cha...

CH and CC bond activations of terminal alkynes in the presence of a butterfly-shaped heteronuclear R...

Synthetic, Mechanistic, and Theoretical Studies on the Generation of Iridium Hydride Alkylidene and ...

Understanding and Predicting Distorted T- versus Y-Geometries for Neutral Chromous Complexes Support...

The hydrogenation reaction of [Ru3(CO)10(C6F5)2P(CH2)2P(C6F5)2]: Migration of a C6F5 group from a ph...

The reaction of [Ru3(CO)12] with bis(diphenylphosphino)amine. The crystal and molecular structure of...

Pyrolysis of [Ru3(CO)10(dppe)]: activation of C?H and P?Ph bonds.: The crystal structure and dynamic...

Reactivity of [Os3(CO)10(NCMe)2] and [Os3(CO)10(?-Cl)(?-AuPPh3)] with 4-mercaptopyridine: X-ray stru...

The reaction of [H4Ru4(CO)12] with 1-penten-3-yne: dimerization and trimerization through the triple...

Metallacyclic Pyridylidene Structures from Reactions of Terminal Pyridylidenes with Alkenes and Acet...