Producción Científica Profesorado

Study on the intramolecular transannular chalcogentin interactions in dithiastannecine compounds.



Cruz Borbolla, Julian

2012

Diego Martínez-Otero, José G. Alvarado-Rodríguez, Julián Cruz-Borbolla, Noemí Andrade-López, Thangarasu Pandiyan, Rafael Moreno-Esparza, Marcos Flores-Alamo, Jesús Cantillo-Castillo, Study on the intramolecular transannular chalcogentin interactions in dithiastannecine compounds, Polyhedron, Año 2012 Volume 33, Issue 1, 9 Pages 367-377, ISSN: 0277-5387, doi.org/10.1016/j.poly.2011.11.053


Abstract


Dithiastannecine compounds of the type [{D(C6H4CH2S)2}SnR1R2] with different donor atoms D were prepared, where D = O and R1 = R2 = Ph (4a); R1 = Ph, R2 = Cl (5a); R1 = n-Bu, R2 = Cl (6a); D = S and R1 = R2 = Ph (4b); R1 = Ph, R2 = Cl (5b); R1 = n-Bu, R2 = Cl (6b). The molecular structures of the monochloro compounds 5a, 5b, 6a, and 6b were established by single-crystal X-ray diffraction and exhibit trigonal bipyramidal geometry at the tin atom with different degrees of distortion being due a D?Sn interaction. The spiro compounds [{D(C6H4CH2S)2}2Sn] with D = O (7a) and D = S (7b) were also synthesized and structurally characterized; the molecular structure of 7a showed the tin atom with a bicapped tetrahedral geometry. The behavior of all tin compounds in solution was investigated by NMR spectroscopy revealing that the D?Sn interaction in solution was practically absent on the basis of the NMR chemical shifts values. DFT calculations with ADF package using VWN/QZ4P were carried out for the 6a and 6b compounds and showed that, in the topological analysis, bond critical points are present along the D-Sn direction



Producto de Investigación




Artículos relacionados

Hypervalence in germanium compounds containing the tetracylic moiety {S(C6H3S)2O}Ge via OGe transann...

Pentacoordination at antimony in dibenzostibocines via DSb transannular interactions (D = O, S): A s...

Mild Oxidation of C?C Bonds of Benzoiridacycles

Synthesis, characterization and crystal structures of organolead dithiolate compounds displaying tra...

Five-membered ring chelate complexes of Ni(II), Pd(II) and Pt(II) derived of di-(2-pyridyl)-N-ethyli...

Synthesis and Relative Stability of a Series of Compounds of Type [Fe(II)(bztpen)X]+, Where bztpen =...

Synthesis and Spectroelectrochemical Studies of Mixed Heteroleptic Chelate Complexes of Ruthenium(II...

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipy...

Structural differences in eight- and ten-membered heterocyclic tin compounds displaying transannular...

Pyrite?Arsenopyrite Galvanic Interaction and Electrochemical Reactivity