Producción Científica Profesorado

CH and CC bond activations of terminal alkynes in the presence of a butterfly-shaped heteronuclear Ru3Au cluster



Sánchez Cabrera, Gloria

2011

CH And CC Bond Activations Of Terminal Alkynes In The Presence Of A Butterfly-Shaped Heteronuclear Ru3Au Cluster. Micaela HernándezSandoval, Francisco J. ZunoCruz, María J. RosalesHoz, Marco A. Leyva, Noemi Andrade, Verónica Salazar, Gloria SánchezCabrera. J. Organomet. Chem. Agosto 2011. Aceptado. ISSN: 0022-328X.. ISSN: 0022-328X.


Abstract


The reaction of compound [Ru3(CO)10(?Cl)(?AuPPh3)] (1) with terminal alkynes HCCR; (R = C6H44CH3, C6H32,5(CH3)2, C6H22,4,5(CH3)3, C(CH3) = CH2, Si(CH3)3), under very mild conditions yielded isostructural compounds [Ru3(CO)9(?AuPPh3)(?3?2?CCR)] (R = C6H44CH3 (2), C6H32,5(CH3)2 (3), C6H22,4,5(CH3)3 (4), C(CH3)CH2 (5), Si(CH3)3) (6)) respectively; where the alkynes suffer oxidative additions to the metallic fragment coordinating as acetylide groups in a ?3?2perpendicular fashion by breaking the C(sp)H bond of the alkynes. The AuPPh3 fragment remains without change in all compounds. All of these clusters have been characterized in solution by i.r. and n.m.r. spectroscopy and their structures have been established by single crystal Xray diffraction studies.



Producto de Investigación




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