Diastereomeric C-glycosyloxanthrones from picramnia antidesma
Rojas Lima, Susana
1999
María del Rosario Hernández-Medel, Claudia O. Ramírez-Corzas, M. Nalleli Rivera-Domínguez, Julieta Ramírez-Mendez, Rosa L. Santillan Baca and Susana Rojas-Lima, Diastereomeric C-glycosyloxanthrones from Picramia antidesma, Phytochemistry, 50, 1379-1383 (1999). DOI: http://dx.doi.org/10.1016/S0031-9422(98)00354-9
Abstract
Nine compounds were isolated and identified from the stem of Picramnia antidesma. Two of the isolated compounds: mayoside and saroside, which is new, are diastereoisomeric oxanthrones. The structure of saroside has been obtained on the basis of spectroscopic evidence. The absolute configuration of this diastereoisomeric pair has been determined by CD spectra, and that of saroside was further established by X-ray crystallographic analysis.
Artículos relacionados
Synthesis of new homochiral 2,3-dialkylpiperazines derived from (R)-(?)-phenylglycinol
Synthesis and Structures of some Lithium and Sodium (Aminoalcoholato)hydrido Aluminates
The Structural Chemistry of N-Monolithium Borazines
Facile synthesis of 1,3,6-oxadiazepines from 2,2?-(1,2-ethanediyldiimino)bisphenols
Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.