Producción Científica Profesorado

Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions



Alvarez Hernandez, Alejandro

1992

Alvarez Hernández A.; Guzmán A.; Ruiz, A.; Velarde, E.; Muchowski J. M. Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions. Journal of Organic Chemistry, 1992, 57, 1653-1656. ISSN 0022-3263. The American Chemical Society, Washington, Estados Unidos de América.


Abstract


Efficacious methods for the synthesis of 3-arylpyrroles or 3-pyrrolylacetylenes are described based on the palladium-catalyzed coupling of appropriate 1-(triisopropylsilyl)-3-substituted pyrroles with aryl halides or monosubstituted acetylenes and subsequent tetrabutylammonium fluoride desilylation.






Artículos relacionados

Structure-Activity Relationships for Inhibition of Cysteine Protease Activity and Development of Pla...

3-Benzoyl-2-isopropyl-4-alkyloxazolidin-5-ones as Efficient and Inexpensive Sources of Enantiopure ?...

Synthesis and Structures of some Lithium and Sodium (Aminoalcoholato)hydrido Aluminates

Study of the reactivity of squarylferrocenes. Addition of amines and aminoesters

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

A practical access to acyl radicals from acyl hydrazides

Further insight into three center hydrogen bonding. Participation in tautomeric equilibria of hetero...

Enantioselective synthesis of ?-amino acids. Part 10: Preparation of novel ?,?- and ?,?-disubstitute...

Synthesis, crystal structures, and quadratic nonlinear optical properties in a series of pushpull bo...

O-benzyl-N-(2-furoyl)thiocarbamate