Producción Científica Profesorado

Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions



Alvarez Hernandez, Alejandro

1992

Alvarez Hernández A.; Guzmán A.; Ruiz, A.; Velarde, E.; Muchowski J. M. Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions. Journal of Organic Chemistry, 1992, 57, 1653-1656. ISSN 0022-3263. The American Chemical Society, Washington, Estados Unidos de América.


Abstract


Efficacious methods for the synthesis of 3-arylpyrroles or 3-pyrrolylacetylenes are described based on the palladium-catalyzed coupling of appropriate 1-(triisopropylsilyl)-3-substituted pyrroles with aryl halides or monosubstituted acetylenes and subsequent tetrabutylammonium fluoride desilylation.






Artículos relacionados

X-ray crystallographic study of neutral boron chelates with ?-diketones and tropolone

3-Benzoyl-2-isopropyl-4-alkyloxazolidin-5-ones as Efficient and Inexpensive Sources of Enantiopure ?...

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)

Synthesis of new homochiral 2,3-dialkylpiperazines derived from (R)-(?)-phenylglycinol

Highly diastereoselective alkylation, acylation and aldol condensation of cis- and trans-(N-acyloyl)...

ChemInform Abstract: Facile Preparation of [4.4]Metacyclophane- and [5.5]Paracyclophane-Type Macrocy...

Synthesis of nitrogen-, oxygen- and sulphur-containing tripodal ligands with a trimethylbenzene core...

Further insight into three center hydrogen bonding. Participation in tautomeric equilibria of hetero...

Cathepsins X and B Can Be Differentiated through Their Respective Mono- and Dipeptidyl Carboxypeptid...