Producción Científica Profesorado

Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions



Alvarez Hernandez, Alejandro

1992

Alvarez Hernández A.; Guzmán A.; Ruiz, A.; Velarde, E.; Muchowski J. M. Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions. Journal of Organic Chemistry, 1992, 57, 1653-1656. ISSN 0022-3263. The American Chemical Society, Washington, Estados Unidos de América.


Abstract


Efficacious methods for the synthesis of 3-arylpyrroles or 3-pyrrolylacetylenes are described based on the palladium-catalyzed coupling of appropriate 1-(triisopropylsilyl)-3-substituted pyrroles with aryl halides or monosubstituted acetylenes and subsequent tetrabutylammonium fluoride desilylation.






Artículos relacionados

Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles

X-ray crystallographic study of neutral boron chelates with ?-diketones and tropolone

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reactio

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

Aroylthioureas: new organic ionophores for heavy-metal ion selective electrodes

New boronates prepared from 2,4-pentanedione derived ligands of the NO2 and N2O2 type comparison to...

Preparation of N-aryl-substituted spiro-?-lactams via Staudinger cycloaddition

A flexible access to highly functionalised boronates

Furocoumarins of three species of the genus Dorstenia

Cathepsins X and B Can Be Differentiated through Their Respective Mono- and Dipeptidyl Carboxypeptid...