2007
Susana Rojas-Lima, Lidia Santillán-Sid, Heraclio López-Ruiz and Alejandro Alvarez-Hernández. Diastereoselective Synthesis of Spiro-?-Lactams via Staudinger Reaction. Heterocycles, 2007, 71, 531-542. ISSN 1881-0942. The Japan Institute of Heterocyclic Chemistry. Japón.
Abstract
In this work, eleven new spiro-?-lactams have been prepared using the Staudinger reaction of isomaleimides (1a-d) and carboxylic acids (chloroacetic acid, (-)-menthoxyacetic acid (7) and an oxazolidinone derived acid (10)) in the presence of triphosgene under mild condition. All reactions have been shown to be stereoselective. The new stereogenic centers were assigned by X-ray diffraction.
X-ray crystallographic study of neutral boron chelates with ?-diketones and tropolone
Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.
Structural studies of spiroarsoranes derived from 2-aminophenols
The Structural Chemistry of N-Monolithium Borazines
Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reactio
Synthesis and Structures of some Lithium and Sodium (Aminoalcoholato)hydrido Aluminates